
Cristian Woroch
Ph.D. Student in Chemistry, admitted Autumn 2019
Stanford Student Employee, Stanford Nano Shared Facilities Service Center
All Publications
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SuFEx Activation with Ca(NTf2)(2) : A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides
ORGANIC LETTERS
2020; 22 (11): 4389–94
Abstract
A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a diverse set of sulfamides, sulfamates, and sulfonamides at room temperature under mild conditions. Additionally, we highlight this transformation to parallel medicinal chemistry to generate a broad array of nitrogen-based S(VI) compounds.
View details for DOI 10.1021/acs.orglett.0c01397
View details for Web of Science ID 000538848600065
View details for PubMedID 32459499
View details for PubMedCentralID PMC7294807
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Sulfonamide Synthesis via Calcium Triflimide Activation of Sulfonyl Fluorides
ORGANIC LETTERS
2018; 20 (13): 3943–47
Abstract
A method using calcium triflimide [Ca(NTf2)2] as a Lewis acid to activate sulfonyl fluorides toward nucleophilic addition with amines is described. The reaction converts a wide array of sterically and electronically diverse sulfonyl fluorides and amines into the corresponding sulfonamides in good yield.
View details for DOI 10.1021/acs.orglett.8b01520
View details for Web of Science ID 000438469500052
View details for PubMedID 29888600