All Publications


  • Concentrated mixed cation acetate "water-in-salt" solutions as green and low-cost high voltage electrolytes for aqueous batteries ENERGY & ENVIRONMENTAL SCIENCE Lukatskaya, M. R., Feldblyum, J. I., Mackanic, D. G., Lissel, F., Michels, D. L., Cui, Y., Bao, Z. 2018; 11 (10): 2876–83

    View details for DOI 10.1039/c8ee00833g

    View details for Web of Science ID 000448339100011

  • A Dual-Crosslinking Design for Resilient Lithium-Ion Conductors. Advanced materials (Deerfield Beach, Fla.) Lopez, J., Sun, Y., Mackanic, D. G., Lee, M., Foudeh, A. M., Song, M., Cui, Y., Bao, Z. 2018: e1804142

    Abstract

    Solid-state electrolyte materials are attractive options for meeting the safety and performance needs of advanced lithium-based rechargeable battery technologies because of their improved mechanical and thermal stability compared to liquid electrolytes. However, there is typically a tradeoff between mechanical and electrochemical performance. Here an elastic Li-ion conductor with dual covalent and dynamic hydrogen bonding crosslinks is described to provide high mechanical resilience without sacrificing the room-temperature ionic conductivity. A solid-state lithium-metal/LiFePO4 cell with this resilient electrolyte can operate at room temperature with a high cathode capacity of 152 mAh g-1 for 300 cycles and can maintain operation even after being subjected to intense mechanical impact testing. This new dual crosslinking design provides robust mechanical properties while maintaining ionic conductivity similar to state-of-the-art polymer-based electrolytes. This approach opens a route toward stable, high-performance operation of solid-state batteries even under extreme abuse.

    View details for PubMedID 30199111

  • Crosslinked Poly(tetrahydrofuran) as a Loosely Coordinating Polymer Electrolyte ADVANCED ENERGY MATERIALS Mackanic, D. G., Michaels, W., Lee, M., Feng, D., Lopez, J., Qin, J., Cui, Y., Bao, Z. 2018; 8 (25)