Bianxiao Cui, Doctoral Dissertation Advisor (AC)
Redesign of a Pyrylium Photoredox Catalyst and Its Application to the Generation of Carbonyl Ylides.
2017; 19 (11): 2989-2992
We report the exploration into photoredox generation of carbonyl ylides from benzylic epoxides using newly designed 4-mesityl-2,6-diphenylpyrylium tetrafluoroborate (MDPT) and 4-mesityl-2,6-di-p-tolylpyrylium tetrafluoroborate (MD(p-tolyl)PT) catalysts. These catalysts are excited at visible wavelengths, are highly robust, and exhibit some of the highest oxidation potentials reported. Their utility was demonstrated in the mild and efficient generation of carbonyl ylides from benzylic epoxides that otherwise could not be carried out by current common photoredox catalysts.
View details for DOI 10.1021/acs.orglett.7b01222
View details for PubMedID 28530103