Stanford Advisors

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All Publications

  • Semi-paracrystallinity in semi-conducting polymers. Materials horizons Marina, S., Gutierrez-Fernandez, E., Gutierrez, J., Gobbi, M., Ramos, N., Solano, E., Rech, J., You, W., Hueso, L., Tercjak, A., Ade, H., Martin, J. 1800


    Precise determination of structural organization of semi-conducting polymers is of paramount importance for the further development of these materials in organic electronic technologies. Yet, prior characterization of some of the best-performing materials for transistor and photovoltaic applications, which are based on polymers with rigid backbones, often resulted in conundrums in which X-ray scattering and microscopy yielded seemingly contradicting results. Here we solve the paradox by introducing a new structural model, i.e., semi-paracrystalline organization. The model establishes that the microstructure of these materials relies on a dense array of small paracrystalline domains embedded in a more disordered matrix. Thus, the overall structural order relies on two parameters: the novel concept of degree of paracrystallinity (i.e., paracrystalline volume/mass fraction, introduced here for the first time) and the lattice distortion parameter of paracrystalline domains (g-parameter from X-ray scattering). Structural parameters of the model are correlated with long-range charge carrier transport, revealing that charge transport in semi-paracrystalline materials is particularly sensitive to the interconnection of paracrystalline domains.

    View details for DOI 10.1039/d1mh01349a

    View details for PubMedID 34984421

  • Resolving the Molecular Origin of Mechanical Relaxations in Donor-Acceptor Polymer Semiconductors ADVANCED FUNCTIONAL MATERIALS Balar, N., Rech, J., Siddika, S., Song, R., Schrickx, H. M., Sheikh, N., Ye, L., Bonilla, A., Awartani, O., Ade, H., You, W., O'Connor, B. T. 2021
  • Designing Simple Conjugated Polymers for Scalable and Efficient Organic Solar Cells CHEMSUSCHEM Rech, J., Neu, J., Qin, Y., Samson, S., Shanahan, J., Josey, R. F., Ade, H., You, W. 2021; 14 (17): 3561-3568


    Conjugated polymers have a long history of exploration and use in organic solar cells, and over the last twenty-five years, marked increases in the solar cell efficiency have been achieved. However, the synthetic complexity of these materials has also drastically increased, which makes the scalability of the highest-efficiency materials difficult. If conjugated polymers could be designed to exhibit both high efficiency and straightforward synthesis, the road to commercial reality would be more achievable. For that reason, a new synthetic approach was designed towards PTQ10 (=poly[(thiophene)-alt-(6,7-difluoro-2-(2-hexyldecyloxy)quinoxaline)]). The new synthetic approach to make PTQ10 brought a significant reduction in cost (1/7th the original) and could also easily accommodate different side chains to move towards green processing solvents. Furthermore, high-efficiency organic solar cells were demonstrated with a PTQ10:Y6 blend exhibiting approximately 15‚ÄČ% efficiency.

    View details for DOI 10.1002/cssc.202100910

    View details for Web of Science ID 000659752200001

    View details for PubMedID 34008311

  • Mantis shrimp-inspired organic photodetector for simultaneous hyperspectral and polarimetric imaging SCIENCE ADVANCES Altaqui, A., Sen, P., Schrickx, H., Rech, J., Lee, J., Escuti, M., You, W., Kim, B. J., Kolbas, R., O'Connor, B. T., Kudenov, M. 2021; 7 (10)


    Combining hyperspectral and polarimetric imaging provides a powerful sensing modality with broad applications from astronomy to biology. Existing methods rely on temporal data acquisition or snapshot imaging of spatially separated detectors. These approaches incur fundamental artifacts that degrade imaging performance. To overcome these limitations, we present a stomatopod-inspired sensor capable of snapshot hyperspectral and polarization sensing in a single pixel. The design consists of stacking polarization-sensitive organic photovoltaics (P-OPVs) and polymer retarders. Multiple spectral and polarization channels are obtained by exploiting the P-OPVs' anisotropic response and the retarders' dispersion. We show that the design can sense 15 spectral channels over a 350-nanometer bandwidth. A detector is also experimentally demonstrated, which simultaneously registers four spectral channels and three polarization channels. The sensor showcases the myriad degrees of freedom offered by organic semiconductors that are not available in inorganics and heralds a fundamentally unexplored route for simultaneous spectral and polarimetric imaging.

    View details for DOI 10.1126/sciadv.abe3196

    View details for Web of Science ID 000625411900007

    View details for PubMedID 33658196

    View details for PubMedCentralID PMC7929508

  • Effects of linking units on fused-ring electron acceptor dimers JOURNAL OF MATERIALS CHEMISTRY A Cai, G., Xiao, Y., Li, M., Rech, J., Wang, J., Liu, K., Lu, X., Tang, Z., Lian, J., Zeng, P., Wang, Y., You, W., Zhan, X. 2020; 8 (27): 13735-13741

    View details for DOI 10.1039/d0ta03058a

    View details for Web of Science ID 000548452100030