John is a postdoctoral scholar in the Department of Materials Science and Engineering at Stanford University in the group of Professor Jennifer A. Dionne. John completed his Ph.D. in June 2018 at the University of California, Los Angeles in the Department of Chemistry and Biochemistry where he was advised by Professor Paul S. Weiss and received his B.S. in Chemistry in 2011 from the University of Florida. John’s dissertation research focused on understanding enantioselective and spin-dependent interactions between chiral biomolecules and electrons in charge transfer and transmission through DNA, alpha-helical peptides, and proteins. John has experience in large-scale molecular self-assembly, chemical patterning, and surface characterization, as well as in biosensor design based on DNA aptamer-functionalized field-effect transistors to measure concentration flux of small molecules such as dopamine and serotonin within physiologically relevant environments. John’s work was recognized by the Physical Chemistry Dissertation Award and George Gregory Award for Research in Physical Chemistry at UCLA in 2018, and was supported during 2017-2018 by a Dissertation Year Fellowship and Feinberg Graduate School Visiting Fellowship Award that enabled a research stay abroad at the Weizmann Institute in Israel hosted by collaborator Professor Ron Naaman in the Department of Chemical and Biological Physics.

Honors & Awards

  • Physical Chemistry Dissertation Award, University of California Los Angeles (2018)
  • George Gregory Award for Research in Physical Chemistry, University of California Los Angeles (2018)
  • Dissertation Year Fellowship Award, University of California Los Angeles (2017)
  • Feinberg Graduate School Visiting Fellowship Award, Weizmann Institute of Science (2017)
  • Colloids and Surface Science Poster Award, 251st American Chemical Society National Meeting (2016)
  • Graduate Research Poster Award, Seaborg Symposium, University of California Los Angeles (2016)
  • Research Showcase Travel Award, University of California Los Angeles (2015)
  • Graduate Dean's Fellowship Award, University of California Los Angeles (2012)

Professional Education

  • Doctor of Philosophy, University of California Los Angeles (2018)
  • Master of Science, University of California Los Angeles (2013)
  • Bachelor of Science, University of Florida (2011)

Current Research and Scholarly Interests

John's research interests include the theoretical design and experimental implementation of dielectric metasurface platforms to interact with light for enhancing electromagnetic near fields that possess enhanced chiral character greater than circularly polarized light for molecular detection, advanced spectroscopies, and spin- and valleytronic integration.

All Publications

  • Spin-Dependent Ionization of Chiral Molecular Films Journal of the American Chemical Society Abendroth, J. M., Cheung, K. M., Stemer, D. M., El Hadri, M. S., Zhao, C., Fullerton, E. E., Weiss, P. S. 2019; 141 (9): 3863–74

    View details for DOI 10.1021/jacs.8b08421

  • Small-Molecule Patterning via Prefunctionalized Alkanethiols CHEMISTRY OF MATERIALS Cao, H. H., Nakatsuka, N., Deshayes, S., Abendroth, J. M., Yang, H., Weiss, P. S., Kasko, A. M., Andrews, A. M. 2018; 30 (12): 4017–30
  • Aptamer-Field-Effect Transistors Overcome Debye Length Limitations for Small-Molecule Sensing Science Nakatsuka, N., Yang, K., Abendroth, J. M., Cheung, K. M., Xu, X., Yang, H., Zhao, C., Zhu, B., Rim, Y., Yang, Y., Weiss, P. S., Stojanović, M. N., Andrews, A. M. 2018; 362 (6412): 319-24

    View details for DOI 10.1126/science.aao6750

  • Analyzing Spin Selectivity in DNA-Mediated Charge Transfer via Fluorescence Microscopy ACS NANO Abendroth, J. M., Nakatsuka, N., Ye, M., Kim, D., Fullertor, E. E., Andrews, A. M., Weiss, P. S. 2017; 11 (7): 7516–26


    Understanding spin-selective interactions between electrons and chiral molecules is critical to elucidating the significance of electron spin in biological processes and to assessing the potential of chiral assemblies for organic spintronics applications. Here, we use fluorescence microscopy to visualize the effects of spin-dependent charge transport in self-assembled monolayers of double-stranded DNA on ferromagnetic substrates. Patterned DNA arrays provide background regions for every measurement to enable quantification of substrate magnetization-dependent fluorescence due to the chiral-induced spin selectivity effect. Fluorescence quenching of photoexcited dye molecules bound within DNA duplexes is dependent upon the rate of charge separation/recombination upon photoexcitation and the efficiency of DNA-mediated charge transfer to the surface. The latter process is modulated using an external magnetic field to switch the magnetization orientation of the underlying ferromagnetic substrates. We discuss our results in the context of the current literature on the chiral-induced spin selectivity effect across various systems.

    View details for DOI 10.1021/acsnano.7b04165

    View details for Web of Science ID 000406649700102

    View details for PubMedID 28672111

  • Polymer-Pen Chemical Lift-Off Lithography NANO LETTERS Xu, X., Yang, Q., Cheung, K. M., Zhao, C., Wattanatorn, N., Belling, J. N., Abendroth, J. M., Slaughter, L. S., Mirkin, C. A., Andrews, A. M., Weiss, P. S. 2017; 17 (5): 3302–11


    We designed and fabricated large arrays of polymer pens having sub-20 nm tips to perform chemical lift-off lithography (CLL). As such, we developed a hybrid patterning strategy called polymer-pen chemical lift-off lithography (PPCLL). We demonstrated PPCLL patterning using pyramidal and v-shaped polymer-pen arrays. Associated simulations revealed a nanometer-scale quadratic relationship between contact line widths of the polymer pens and two other variables: polymer-pen base line widths and vertical compression distances. We devised a stamp support system consisting of interspersed arrays of flat-tipped polymer pens that are taller than all other sharp-tipped polymer pens. These supports partially or fully offset stamp weights thereby also serving as a leveling system. We investigated a series of v-shaped polymer pens with known height differences to control relative vertical positions of each polymer pen precisely at the sub-20 nm scale mimicking a high-precision scanning stage. In doing so, we obtained linear-array patterns of alkanethiols with sub-50 nm to sub-500 nm line widths and minimum sub-20 nm line width tunable increments. The CLL pattern line widths were in agreement with those predicted by simulations. Our results suggest that through informed design of a stamp support system and tuning of polymer-pen base widths, throughput can be increased by eliminating the need for a scanning stage system in PPCLL without sacrificing precision. To demonstrate functional microarrays patterned by PPCLL, we inserted probe DNA into PPCLL patterns and observed hybridization by complementary target sequences.

    View details for DOI 10.1021/acs.nanolett.7b01236

    View details for Web of Science ID 000401307300082

    View details for PubMedID 28409640

  • Surface Structure and Electron Transfer Dynamics of the Self-Assembly of Cyanide on Au{111} Journal of Physical Chemistry C Guttentag, A. I., Waechter, T., Barr, K. K., Abendroth, J. M., Song, T., Sullivan, N. F., Yang, Y., Allara, D. L., Zharnikov, M., Weiss, P. S. 2016; 120 (47): 26736–46
  • Controlling Motion at the Nanoscale: Rise of the Molecular Machines ACS NANO Abendroth, J. M., Bushuyev, O. S., Weiss, P. S., Barrett, C. J. 2015; 9 (8): 7746–68


    As our understanding and control of intra- and intermolecular interactions evolve, ever more complex molecular systems are synthesized and assembled that are capable of performing work or completing sophisticated tasks at the molecular scale. Commonly referred to as molecular machines, these dynamic systems comprise an astonishingly diverse class of motifs and are designed to respond to a plethora of actuation stimuli. In this Review, we outline the conditions that distinguish simple switches and rotors from machines and draw from a variety of fields to highlight some of the most exciting recent examples of opportunities for driven molecular mechanics. Emphasis is placed on the need for controllable and hierarchical assembly of these molecular components to display measurable effects at the micro-, meso-, and macroscales. As in Nature, this strategy will lead to dramatic amplification of the work performed via the collective action of many machines organized in linear chains, on functionalized surfaces, or in three-dimensional assemblies.

    View details for DOI 10.1021/acsnano.5b03367

    View details for Web of Science ID 000360323300004

    View details for PubMedID 26172380

  • Halide Anions as Shape-Directing Agents for Obtaining High-Quality Anisotropic Gold Nanostructures CHEMISTRY OF MATERIALS DuChene, J. S., Niu, W., Abendroth, J. M., Sun, Q., Zhao, W., Huo, F., Wei, W. 2013; 25 (8): 1392–99

    View details for DOI 10.1021/cm3020397

    View details for Web of Science ID 000318144000023