Stanford University


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  • John R Peck

    John R Peck

    Winter CSP Instructor

    BioJohn Peck teaches portrait and figure drawing for Stanford Continuing Studies.

    His paintings and drawings can be seen in private collections and galleries in London, Florence, Dublin, and Santa Fe. He graduated from the Florence Academy of Art and received an MArch from the University of New Mexico, where he was an instructor in the School of Architecture and Planning. He is the co-author of “Drawing in Space: A Manual for Figurative Sculpture.”

    His work can be viewed at www.johnpeck.com

  • Sadia Peck

    Sadia Peck

    Affiliate, Central Mgmt-Misc AR

    BioSadia Peck is a Certified Registered Nurse Anesthestist at Stanford Health Care. She graduated with her Master of Science in Nursing (MSN) from California State University, Fullerton/ Kaiser Permanente School of Anesthesia. Prior to obtaining her MSN, she obtained both her Masters in Health Administration and Bachelor of Science in Nursing from Florida Atlantic University. She also has a Bachelor of Science in Microbiology from the University of Florida. Her area of specialization is Anesthesia, providing high-quality and compassionate anesthesia care to adult peri-operative patients.

  • Robert Pecora

    Robert Pecora

    Professor of Chemistry, Emeritus

    Current Research and Scholarly InterestsThe development of the basic principles behind the dynamic light scattering (DLS) technique and its application to a wide variety of liquid systems is one of Pecora's outstanding contributions to physical chemistry. DLS is now an indispensable tool in the repertoire of polymer, colloid and biophysical chemists. It is generally accepted to be one of the best methods for measuring the mutual diffusion coefficients and, in dilute systems, the hydrodynamic sizes of polymers and particulates in solution or suspension. It is widely used, among other things, for studying size distributions of polymer and colloid dispersions; for testing theories of polymer dynamics in dilute and concentrated systems; and for studying interactions between macromolecules and colloidal particles in liquid dispersions. The basic work that established the foundation of this technique was done in the 1960s. Pecora has revisited this area over the years-formulating theories, for instance, of scattering from hollow spheres, large cylindrically symmetric molecules and wormlike chains.

    An experimental program began in the early seventies resulted in a now classic series of studies on the rotational dynamics of small molecules in liquids. This work, utilizing mainly depolarized DLS and carbon 13 nuclear magnetic relaxation, has had a wide impact in the area of liquid state dynamics.

    It was also during this period that the theoretical foundation for the fluorescence correlation spectroscopy technique (FCS) was formulated. Because of recent advances in equipment and materials, this technique has recently been revived and is now a powerful tool in biophysics.

    The experimental and theoretical techniques developed for the study of the dynamics of relatively simple small molecule liquids have been used to investigate more complex systems such as the rotation of small molecule solvents in glassy and amorphous polymers. The resonance- enhanced depolarized light scattering technique was also developed in this period.

    Extensive studies using depolarized dynamic light scattering (using the Fabry-Perot interferometer) as well as photon correlation spectroscopy, NMR, FCS and small angle X-ray scattering to the dynamics of oligonucleotides have determined the hydrodynamic diameter of DNA and the internal bending angles of the bases. They also provided support for relations relating hydrodynamic parameters to molecular dimensions for short rodlike molecules and “polyelectrolyte effects” on the translational and rotational motions of these highly charged molecules.

    A major area of experimental and theoretical study has been the study of the dynamics of rigid and semirigid rodlike polymers in both dilute and semidilute dispersions. The work on translation and rotation of poly (-benzyl-L-glutamate) in semidilute solution is a foremost early work in this area.

    The Pecora group has synthesized and studied the dynamics of model
    rigid rod/sphere composite liquids. Studies of the translation of dilute spheres through solutions of the rods as functions of the rod and sphere sizes and the rod concentrations have provided the stimulus for more experiment and theoretical work in this area. Transient electric birefringence decay studies of the rotation of dilute rigid rod polymers in suspensions of comparably sized spherical particles have revealed scaling laws for the rod rotation.

    A unique feature of part of this work on rigid and semirigid rodlike polymers is the utilization of genetic engineering techniques to construct a monodisperse, homologous series of DNA restriction fragments. These biologically-produced fragments have served as well-characterized model macromolecules for solution studies of the dynamics of semirigid rodlike polymers.

    The well-regarded book of Pecora and Berne on dynamic light scattering, first published in 1976, has become a major reference work. It is now a Dover paperback.