Bio


SLAC Director Chi-Chang Kao, a noted X-ray scientist, came to SLAC in 2010 to serve as associate laboratory director for the Stanford Synchrotron Radiation Lightsource. He became SLAC’s fifth director in November 2012.

Previously, Kao served for five years as chairperson of the National Synchrotron Light Source at Brookhaven National Laboratory in New York. He undertook major upgrades to the light source's scientific programs and experimental facilities while developing potential science programs for NSLS-II, one of the newest and most advanced synchrotron facilities in the world. His research focuses on X-ray physics, superconductivity, magnetic materials and the properties of materials under high pressure.

Kao earned a bachelor's degree in chemical engineering in 1980 from National Taiwan University and a doctorate in chemical engineering from Cornell University in 1988. He joined Brookhaven shortly afterward, working his way from NSLS postdoctoral research assistant to chair. Kao also served as an adjunct professor in the Department of Physics and Astronomy at Stony Brook University.

He was elected a fellow of the American Physical Society in 2006 and was named a fellow of the American Association for the Advancement of Science in 2010 for his many contributions to resonant elastic and inelastic X-ray scattering techniques and their application to materials physics, as well as for his leadership at the NSLS.

Academic Appointments


  • Professor, Photon Science Directorate

Professional Education


  • Ph.D., Cornell, Chemical Engineering (1988)

All Publications


  • Detection of the Chiral Spin Structure in Ferromagnetic SrRuO3 Thin Film ACS APPLIED MATERIALS & INTERFACES Huang, H., Lee, S., Kim, B., Sohn, B., Kim, C., Kao, C., Lee, J. 2020; 12 (33): 37757–63

    Abstract

    SrRuO3 (SRO) thin films and their heterostructure have attracted much attention because of the recently demonstrated fascinating properties, such as topological Hall effect and skyrmions. Critical to the understanding of those SRO properties is the study of the spin configuration. Here, we conduct resonant soft X-ray scattering (RSXS) at the oxygen K edge to investigate the spin configuration of a four-unit-cell SRO film that was grown epitaxially on a single-crystal SrTiO3. The RSXS signal under a magnetic field (∼0.4 tesla) clearly shows a magnetic dichroism pattern around the specular reflection. Model calculations on the RSXS signal demonstrate that the magnetic dichroism pattern originates from a Néel-type chiral spin structure in this SRO thin film. We believe that the observed spin structure of the SRO system is a critical piece of information for understanding its intriguing magnetic and transport properties.

    View details for DOI 10.1021/acsami.0c10545

    View details for Web of Science ID 000563074900095

    View details for PubMedID 32696641

  • A role for subducted super-hydrated kaolinite in Earth's deep water cycle NATURE GEOSCIENCE Hwang, H., Seoung, D., Lee, Y., Liu, Z., Liermann, H., Cynn, H., Vogt, T., Kao, C., Mao, H. 2017; 10 (12): 947-+
  • Pressure-Dependent Structural and Chemical Changes in a Metal-Organic Framework with One-Dimensional Pore Structure CHEMISTRY OF MATERIALS Im, J., Seoung, D., Hwang, G. C., Jun, J. W., Jhung, S. H., Kao, C., Vogt, T., Lee, Y. 2016; 28 (15): 5336-5341
  • Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework Cations CHEMISTRY OF MATERIALS Seoung, D., Lee, Y., Kao, C., Vogt, T., Lee, Y. 2015; 27 (11): 3874-3880
  • Pressure-Induced Metathesis Reaction To Sequester Cs ENVIRONMENTAL SCIENCE & TECHNOLOGY Im, J., Seoung, D., Lee, S. Y., Blom, D. A., Vogt, T., Kao, C., Lee, Y. 2015; 49 (1): 513-519

    Abstract

    We report here a pressure-driven metathesis reaction where Ag-exchanged natrolite (Ag16Al16Si24O80·16H2O, Ag-NAT) is pressurized in an aqueous CsI solution, resulting in the exchange of Ag(+) by Cs(+) in the natrolite framework forming Cs16Al16Si24O80·16H2O (Cs-NAT-I) and, above 0.5 GPa, its high-pressure polymorph (Cs-NAT-II). During the initial cation exchange, the precipitation of AgI occurs. Additional pressure and heat at 2 GPa and 160 °C transforms Cs-NAT-II to a pollucite-related, highly dense, and water-free triclinic phase with nominal composition CsAlSi2O6. At ambient temperature after pressure release, the Cs remains sequestered in a now monoclinic pollucite phase at close to 40 wt % and a favorably low Cs leaching rate under back-exchange conditions. This process thus efficiently combines the pressure-driven separation of Cs and I at ambient temperature with the subsequent sequestration of Cs under moderate pressures and temperatures in its preferred waste form suitable for long-term storage at ambient conditions. The zeolite pollucite CsAlSi2O6·H2O has been identified as a potential host material for nuclear waste remediation of anthropogenic (137)Cs due to its chemical and thermal stability, low leaching rate, and the large amount of Cs it can contain. The new water-free pollucite phase we characterize during our process will not display radiolysis of water during longterm storage while maintaining the Cs content and low leaching rate.

    View details for DOI 10.1021/es504659z

    View details for Web of Science ID 000347589300059

    View details for PubMedID 25515673

  • Atomically Engineered Metal Insulator Transition at the TiO2/LaAlO3 Heterointerface NANO LETTERS Minohara, M., Tachikawa, T., Nakanishi, Y., Hikita, Y., Kourkoutis, L. F., Lee, J., Kao, C., Yoshita, M., Akiyama, H., Bell, C., Hwang, H. Y. 2014; 14 (11): 6743-6746

    Abstract

    We demonstrate that the atomic boundary conditions of simple binary oxides can be used to impart dramatic changes of state. By changing the substrate surface termination of LaAlO3 (001) from AlO2 to LaO, the room-temperature sheet conductance of anatase TiO2 films are increased by over 3 orders of magnitude, transforming the intrinsic insulating state to a high mobility metallic state, while maintaining excellent optical transparency.

    View details for DOI 10.1021/nl5039192

    View details for Web of Science ID 000345723800113

    View details for PubMedID 25343440

  • Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures NATURE CHEMISTRY Seoung, D., Lee, Y., Cynn, H., Park, C., Choi, K., Blom, D. A., Evans, W. J., Kao, C., Vogt, T., Lee, Y. 2014; 6 (9): 835-839

    Abstract

    Pressure drastically alters the chemical and physical properties of materials and allows structural phase transitions and chemical reactions to occur that defy much of our understanding gained under ambient conditions. Particularly exciting is the high-pressure chemistry of xenon, which is known to react with hydrogen and ice at high pressures and form stable compounds. Here, we show that Ag16Al16Si24O8·16H2O (Ag-natrolite) irreversibly inserts xenon into its micropores at 1.7 GPa and 250 °C, while Ag(+) is reduced to metallic Ag and possibly oxidized to Ag(2+). In contrast to krypton, xenon is retained within the pores of this zeolite after pressure release and requires heat to desorb. This irreversible insertion and trapping of xenon in Ag-natrolite under moderate conditions sheds new light on chemical reactions that could account for the xenon deficiency relative to argon observed in terrestrial and Martian atmospheres.

    View details for DOI 10.1038/NCHEM.1997

    View details for Web of Science ID 000341373500022

    View details for PubMedID 25143221

  • Super-Hydrated Zeolites: Pressure-Induced Hydration in Natrolites CHEMISTRY-A EUROPEAN JOURNAL Seoung, D., Lee, Y., Kao, C., Vogt, T., Lee, Y. 2013; 19 (33): 10876-10883

    Abstract

    High-pressure synchrotron X-ray powder diffraction studies of a series of alkali-metal-exchanged natrolites, A16Al16Si24O80·nH2O (A=Li, K, Na, Rb, and Cs and n=14, 16, 22, 24, 32), in the presence of water, reveal structural changes that far exceed what can be achieved by varying temperature and chemical composition. The degree of volume expansion caused by pressure-induced hydration (PIH) is inversely proportional to the non-framework cation radius. The expansion of the unit-cell volume through PIH is as large as 20.6% in Li-natrolite at 1.0 GPa and decreases to 6.7, 3.8, and 0.3% in Na-, K-, and Rb-natrolites, respectively. On the other hand, the onset pressure of PIH appears to increase with non-framework cation radius up to 2.0 GPa in Rb-natrolite. In Cs-natrolite, no PIH is observed but a new phase forms at 0.3 GPa with a 4.8% contracted unit cell and different cation-water configuration in the pores. In K-natrolite, the elliptical channel undergoes a unique overturn upon the formation of super-hydrated natrolite K16Al16Si24O80·32H2O at 1.0 GPa, a species that reverts back above 2.5 GPa as the potassium ions interchange their locations with those of water and migrate from the hinge to the center of the pores. Super-hydrated zeolites are new materials that offer numerous opportunities to expand and modify known chemical and physical properties by reversibly changing the composition and structure using pressure in the presence of water.

    View details for DOI 10.1002/chem.201300591

    View details for Web of Science ID 000322626500020

    View details for PubMedID 23852613

  • Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Sodium Natrolite JOURNAL OF PHYSICAL CHEMISTRY C Lee, Y., Lee, J., Kao, C., Yoon, J., Vogt, T., Lee, Y. 2013; 117 (31): 16119-16126

    View details for DOI 10.1021/jp405360s

    View details for Web of Science ID 000323082300030

  • Resolving Material-Specific Structures within Fe3O4 vertical bar gamma-Mn2O3 Core vertical bar Shell Nanoparticles Using Anomalous Small-Angle X-ray Scattering ACS NANO Krycka, K. L., Borchers, J. A., Salazar-Alvarez, G., Lopez-Ortega, A., Estrader, M., Estrade, S., Winkler, E., Daniel Zysler, R., Sort, J., Peiro, F., Dolors Baro, M., Kao, C., Nogues, J. 2013; 7 (2): 921-931

    View details for DOI 10.1021/nn303600e

    View details for Web of Science ID 000315618700008

  • Thermal Expansion of the Superhydrated Small-Pore Zeolite Natrolite JOURNAL OF PHYSICAL CHEMISTRY C Lee, Y., Kao, C., Vogt, T. 2012; 116 (5): 3286-3291

    View details for DOI 10.1021/jp209514q

    View details for Web of Science ID 000299985300012

  • Immobilization of Large, Aliovalent Cations in the Small-Pore Zeolite K-Natrolite by Means of Pressure ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Lee, Y., Lee, Y., Seoung, D., Im, J., Hwang, H., Kim, T., Liu, D., Liu, Z., Lee, S. Y., Kao, C., Vogt, T. 2012; 51 (20): 4848-4851

    Abstract

    High-pressure ion exchange of small-pore zeolite K-natrolite allows immobilization of nominally non-exchangeable aliovalent cations such as trivalent europium. A sample exchanged at 3.0(1) GPa and 250 °C contains about 4.7 Eu(III) ions per unit cell, which is equivalent to over 90 % of the K(+) cations being exchanged.

    View details for DOI 10.1002/anie.201201045

    View details for Web of Science ID 000303925200010

    View details for PubMedID 22473627

  • Pressure- and Heat-Induced Insertion of CO2 into an Auxetic Small-Pore Zeolite JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Lee, Y., Liu, D., Seoung, D., Liu, Z., Kao, C., Vogt, T. 2011; 133 (6): 1674-1677

    Abstract

    When the small-pore zeolite natrolite is compressed at ca. 1.5 GPa and heated to ca. 110 °C in the presence of CO(2), the unit cell volume of natrolite expands by 6.8% and ca. 12 wt % of CO(2) is contained in the expanded elliptical channels. This CO(2) insertion into natrolite is found to be reversible upon pressure release.

    View details for DOI 10.1021/ja109765d

    View details for Web of Science ID 000287831800017

    View details for PubMedID 21268577

  • In-situ dehydration studies of fully K-,Rb-, and Cs-exchanged natrolites AMERICAN MINERALOGIST Lee, Y., Seoung, D., Liu, D., Park, M. B., Hong, S. B., Chen, H., Bai, J., Kao, C., Vogt, T., Lee, Y. 2011; 96 (2-3): 393-401
  • Electronic Structure of Crystalline He-4 at High Pressures PHYSICAL REVIEW LETTERS Mao, H. K., Shirley, E. L., Ding, Y., Eng, P., Cai, Y. Q., Chow, P., Xiao, Y., Shu, J., Hemley, R. J., Kao, C., Mao, W. L. 2010; 105 (18)

    Abstract

    Using inelastic x-ray scattering techniques, we have succeeded in probing the high-pressure electronic structure of helium at 300 K. Helium has the widest known valence-conduction band gap of all materials a property whose high-pressure response has been inaccessible to direct measurements. We observed a rich electron excitation spectrum, including a cutoff edge above 23 eV, a sharp exciton peak showing linear volume dependence, and a series of excitations and continuum at 26 to 45 eV. We determined the electronic dispersion along the Γ-M direction over two Brillouin zones, and provided a quantitative picture of the helium exciton beyond the simplified Wannier-Frenkel description.

    View details for DOI 10.1103/PhysRevLett.105.186404

    View details for Web of Science ID 000283652100003

    View details for PubMedID 21231121

  • High-pressure evolution of Fe2O3 electronic structure revealed by x-ray absorption PHYSICAL REVIEW B Wang, S., Mao, W. L., Sorini, A. P., Chen, C., Devereaux, T. P., Ding, Y., Xiao, Y., Chow, P., Hiraoka, N., Ishii, H., Cai, Y. Q., Kao, C. 2010; 82 (14)
  • Atomic-scale visualization of inertial dynamics SCIENCE Lindenberg, A. M., Larsson, J., Sokolowski-Tinten, K., Gaffney, K. J., Blome, C., Synnergren, O., Sheppard, J., Caleman, C., MacPhee, A. G., Weinstein, D., Lowney, D. P., Allison, T. K., Matthews, T., Falcone, R. W., Cavalieri, A. L., Fritz, D. M., Lee, S. H., Bucksbaum, P. H., Reis, D. A., Rudati, J., Fuoss, P. H., Kao, C. C., Siddons, D. P., Pahl, R., Als-Nielsen, J., Duesterer, S., Ischebeck, R., Schlarb, H., Schulte-Schrepping, H., Tschentscher, T., Schneider, J., von der Linde, D., Hignette, O., Sette, F., Chapman, H. N., Lee, R. W., Hansen, T. N., Techert, S., Wark, J. S., Bergh, M., Huldt, G., van der Spoel, D., Timneanu, N., Hajdu, J., Akre, R. A., Bong, E., Krejcik, P., ARTHUR, J., Brennan, S., Luening, K., Hastings, J. B. 2005; 308 (5720): 392-395

    Abstract

    The motion of atoms on interatomic potential energy surfaces is fundamental to the dynamics of liquids and solids. An accelerator-based source of femtosecond x-ray pulses allowed us to follow directly atomic displacements on an optically modified energy landscape, leading eventually to the transition from crystalline solid to disordered liquid. We show that, to first order in time, the dynamics are inertial, and we place constraints on the shape and curvature of the transition-state potential energy surface. Our measurements point toward analogies between this nonequilibrium phase transition and the short-time dynamics intrinsic to equilibrium liquids.

    View details for DOI 10.1126/science.1107996

    View details for Web of Science ID 000228492000046

    View details for PubMedID 15831753

  • Clocking femtosecond x rays PHYSICAL REVIEW LETTERS Cavalieri, A. L., Fritz, D. M., Lee, S. H., Bucksbaum, P. H., Reis, D. A., Rudati, J., Mills, D. M., Fuoss, P. H., Stephenson, G. B., Kao, C. C., Siddons, D. P., Lowney, D. P., MacPhee, A. G., Weinstein, D., Falcone, R. W., Pahl, R., Als-Nielsen, J., Blome, C., Dusterer, S., Ischebeck, R., Schlarb, H., Schulte-Schrepping, H., Tschentscher, T., Schneider, J., Hignette, O., Sette, F., Sokolowski-Tinten, K., Chapman, H. N., Lee, R. W., Hansen, T. N., Synnergren, O., Larsson, J., Techert, S., Sheppard, J., Wark, J. S., Bergh, M., Caleman, C., Huldt, G., van der Spoel, D., Timneanu, N., Hajdu, J., Akre, R. A., Bong, E., Emma, P., Krejcik, P., ARTHUR, J., Brennan, S., Gaffney, K. J., Lindenberg, A. M., Luening, K., Hastings, J. B. 2005; 94 (11)

    Abstract

    Linear-accelerator-based sources will revolutionize ultrafast x-ray science due to their unprecedented brightness and short pulse duration. However, time-resolved studies at the resolution of the x-ray pulse duration are hampered by the inability to precisely synchronize an external laser to the accelerator. At the Sub-Picosecond Pulse Source at the Stanford Linear-Accelerator Center we solved this problem by measuring the arrival time of each high energy electron bunch with electro-optic sampling. This measurement indirectly determined the arrival time of each x-ray pulse relative to an external pump laser pulse with a time resolution of better than 60 fs rms.

    View details for DOI 10.1103/PhysRevLett.94.114801

    View details for Web of Science ID 000227923200034

    View details for PubMedID 15903864