Qitong Li

All Publications

• Temperature-Dependent Excitonic Light Manipulation with Atomically Thin Optical Elements. Nano letters Guarneri, L., Li, Q., Bauer, T., Song, J. H., Saunders, A. P., Liu, F., Brongersma, M. L., van de Groep, J. 2024

  Abstract

  Monolayer 2D semiconductors, such as WS2, exhibit uniquely strong light-matter interactions due to exciton resonances that enable atomically thin optical elements. Similar to geometry-dependent plasmon and Mie resonances, these intrinsic material resonances offer coherent and tunable light scattering. Thus far, the impact of the excitons' temporal dynamics on the performance of such excitonic metasurfaces remains unexplored. Here, we show how the excitonic decay rates dictate the focusing efficiency of an atomically thin lens carved directly out of exfoliated monolayer WS2. By isolating the coherent exciton radiation from the incoherent background in the focus of the lens, we obtain a direct measure of the role of exciton radiation in wavefront shaping. Furthermore, we investigate the influence of exciton-phonon scattering by characterizing the focusing efficiency as a function of temperature, demonstrating an increased optical efficiency at cryogenic temperatures. Our results provide valuable insights into the role of excitonic light scattering in 2D nanophotonic devices.

  View details for DOI 10.1021/acs.nanolett.4c00694

  View details for PubMedID 38578061

• Determining hot-carrier transport dynamics from terahertz emission. Science (New York, N.Y.) Taghinejad, M., Xia, C., Hrton, M., Lee, K. T., Kim, A. S., Li, Q., Guzelturk, B., Kalousek, R., Xu, F., Cai, W., Lindenberg, A. M., Brongersma, M. L. 2023; 382 (6668): 299-305

  Abstract

  Understanding the ultrafast excitation and transport dynamics of plasmon-driven hot carriers is critical to the development of optoelectronics, photochemistry, and solar-energy harvesting. However, the ultrashort time and length scales associated with the behavior of these highly out-of-equilibrium carriers have impaired experimental verification of ab initio quantum theories. Here, we present an approach to studying plasmonic hot-carrier dynamics that analyzes the temporal waveform of coherent terahertz bursts radiated by photo-ejected hot carriers from designer nano-antennas with a broken symmetry. For ballistic carriers ejected from gold antennas, we find an ~11-femtosecond timescale composed of the plasmon lifetime and ballistic transport time. Polarization- and phase-sensitive detection of terahertz fields further grant direct access to their ballistic transport trajectory. Our approach opens explorations of ultrafast carrier dynamics in optically excited nanostructures.

  View details for DOI 10.1126/science.adj5612

  View details for PubMedID 37856614

• A Purcell-enabled monolayer semiconductor free-space optical modulator NATURE PHOTONICS Li, Q., Song, J., Xu, F., van de Groep, J., Hong, J., Daus, A., Lee, Y., Johnson, A. C., Pop, E., Liu, F., Brongersma, M. L. 2023

  View details for DOI 10.1038/s41566-023-01250-9

  View details for Web of Science ID 001031418200001

• Controlling Valley-Specific Light Emission from Monolayer MoS2 with Achiral Dielectric Metasurfaces. Nano letters Liu, Y., Lau, S. C., Cheng, W., Johnson, A., Li, Q., Simmerman, E., Karni, O., Hu, J., Liu, F., Brongersma, M. L., Heinz, T. F., Dionne, J. A. 2023

  Abstract

  Excitons in two-dimensional transition metal dichalcogenides have a valley degree of freedom that can be optically manipulated for quantum information processing. Here, we integrate MoS2 monolayers with achiral silicon disk array metasurfaces to enhance and control valley-specific absorption and emission. Through the coupling to the metasurface electric and magnetic Mie modes, the intensity and lifetime of the emission of neutral excitons, trions, and defect bound excitons can be enhanced and shortened, respectively, while the spectral shape can be modified. Additionally, the degree of polarization (DOP) of exciton and trion emission from the valley can be symmetrically enhanced at 100 K. The DOP increase is attributed to both the metasurface-enhanced chiral absorption of light and the metasurface-enhanced exciton emission from the Purcell effect. Combining Si-compatible photonic design with large-scale 2D materials integration, our work makes an important step toward on-chip valleytronic applications approaching room-temperature operation.

  View details for DOI 10.1021/acs.nanolett.3c01630

  View details for PubMedID 37347949

• Impact of substrates and quantum effects on exciton line shapes of 2D semiconductors at room temperature NANOPHOTONICS van de Groep, J., Li, Q., Song, J., Kik, P. G., Brongersma, M. L. 2023

  View details for DOI 10.1515/nanoph-2023-0193

  View details for Web of Science ID 001015007800001

• Quantitative phase contrast imaging with a nonlocal angle-selective metasurface. Nature communications Ji, A., Song, J. H., Li, Q., Xu, F., Tsai, C. T., Tiberio, R. C., Cui, B., Lalanne, P., Kik, P. G., Miller, D. A., Brongersma, M. L. 2022; 13 (1): 7848

  Abstract

  Phase contrast microscopy has played a central role in the development of modern biology, geology, and nanotechnology. It can visualize the structure of translucent objects that remains hidden in regular optical microscopes. The optical layout of a phase contrast microscope is based on a 4 f image processing setup and has essentially remained unchanged since its invention by Zernike in the early 1930s. Here, we propose a conceptually new approach to phase contrast imaging that harnesses the non-local optical response of a guided-mode-resonator metasurface. We highlight its benefits and demonstrate the imaging of various phase objects, including biological cells, polymeric nanostructures, and transparent metasurfaces. Our results showcase that the addition of this non-local metasurface to a conventional microscope enables quantitative phase contrast imaging with a 0.02π phase accuracy. At a high level, this work adds to the growing body of research aimed at the use of metasurfaces for analog optical computing.

  View details for DOI 10.1038/s41467-022-34197-6

  View details for PubMedID 36543788

  View details for PubMedCentralID PMC9772391

• Metasurface optofluidics for dynamic control of light fields. Nature nanotechnology Li, Q., van de Groep, J., White, A. K., Song, J., Longwell, S. A., Fordyce, P. M., Quake, S. R., Kik, P. G., Brongersma, M. L. 2022

  Abstract

  The ability to manipulate light and liquids on integrated optofluidics chips has spurred a myriad of important developments in biology, medicine, chemistry and display technologies. Here we show how the convergence of optofluidics and metasurface optics can lead to conceptually new platforms for the dynamic control of light fields. We first demonstrate metasurface building blocks that display an extreme sensitivity in their scattering properties to their dielectric environment. These blocks are then used to create metasurface-based flat optics inside microfluidic channels where liquids with different refractive indices can be directed to manipulate their optical behaviour. We demonstrate the intensity and spectral tuning of metasurface colour pixels as well as on-demand optical elements. We finally demonstrate automated control in an integrated meta-optofluidic platform to open up new display functions. Combined with large-scale microfluidic integration, our dynamic-metasurface flat-optics platform could open up the possibility of dynamic display, imaging, holography and sensing applications.

  View details for DOI 10.1038/s41565-022-01197-y

  View details for PubMedID 36163507

• Fundamental Limitations of Huygens' Metasurfaces for Optical Beam Shaping LASER & PHOTONICS REVIEWS Gigli, C., Li, Q., Chavel, P., Leo, G., Brongersma, M. L., Lalanne, P. 2021

  View details for DOI 10.1002/lpor.202000448

  View details for Web of Science ID 000660500800001

• Structural color from a coupled nanowire pair beyond the bonding and antibonding model OPTICA Li, Q., Wu, T., van de Groep, J., Lalanne, P., Brongersma, M. L. 2021; 8 (4): 464-470

  View details for DOI 10.1364/OPTICA.418888

  View details for Web of Science ID 000642200300006

• Nanoelectromechanical modulation of a strongly-coupled plasmonic dimer. Nature communications Song, J., Raza, S., van de Groep, J., Kang, J., Li, Q., Kik, P. G., Brongersma, M. L. 2021; 12 (1): 48

  Abstract

  The ability of two nearly-touching plasmonic nanoparticles to squeeze light into a nanometer gap has provided a myriad of fundamental insights into light-matter interaction. In this work, we construct a nanoelectromechanical system (NEMS) that capitalizes on the unique, singular behavior that arises at sub-nanometer particle-spacings to create an electro-optical modulator. Using in situ electron energy loss spectroscopy in a transmission electron microscope, we map the spectral and spatial changes in the plasmonic modes as they hybridize and evolve from a weak to a strong coupling regime. In the strongly-coupled regime, we observe a very large mechanical tunability (~250meV/nm) of the bonding-dipole plasmon resonance of the dimer at ~1nm gap spacing, right before detrimental quantum effects set in. We leverage our findings to realize a prototype NEMS light-intensity modulator operating at ~10MHz and with a power consumption of only 4 fJ/bit.

  View details for DOI 10.1038/s41467-020-20273-2

  View details for PubMedID 33397929

• Quantitative Phase Contrast Imaging using Guided-mode Resonator Devices Ji, A., Song, J., Li, Q., Kik, P. G., Miller, D. B., Brongersma, M. L., IEEE IEEE. 2021

  View details for Web of Science ID 000831479803156

• Exciton Resonance Tuning in Atomically-Thin Optical Elements van de Groep, J., Song, J., Li, Q., Celano, U., Kik, P. G., Brongersma, M. L., IEEE IEEE. 2021

  View details for Web of Science ID 000831479802173

• Exciton resonance tuning of an atomically thin lens NATURE PHOTONICS van de Groep, J., Song, J., Celano, U., Li, Q., Kik, P. G., Brongersma, M. L. 2020

  View details for DOI 10.1038/s41566-020-0624-y

  View details for Web of Science ID 000529001600001

• Transparent multispectral photodetectors mimicking the human visual system. Nature communications Li, Q., van de Groep, J., Wang, Y., Kik, P. G., Brongersma, M. L. 2019; 10 (1): 4982

  Abstract

  Compact and lightweight photodetection elements play a critical role in the newly emerging augmented reality, wearable and sensing technologies. In these technologies, devices are preferred to be transparent to form an optical interface between a viewer and the outside world. For this reason, it is of great value to create detection platforms that are imperceptible to the human eye directly onto transparent substrates. Semiconductor nanowires (NWs) make ideal photodetectors as their optical resonances enable parsing of the multi-dimensional information carried by light. Unfortunately, these optical resonances also give rise to strong, undesired light scattering. In this work, we illustrate how a new optical resonance arising from the radiative coupling between arrayed silicon NWs can be harnessed to remove reflections from dielectric interfaces while affording spectro-polarimetric detection. The demonstrated transparent photodetector concept opens up promising platforms for transparent substrates as the base for opto-electronic devices and in situoptical measurement systems.

  View details for DOI 10.1038/s41467-019-12899-8

  View details for PubMedID 31676782

• Spin-Switched Three-Dimensional Full-Color Scenes Based on a Dielectric Meta-hologram ACS PHOTONICS Feng, H., Li, Q., Wan, W., Song, J., Gong, Q., Brongersma, M. L., Li, Y. 2019; 6 (11): 2910–16

  View details for DOI 10.1021/acsphotonics.9b01017

  View details for Web of Science ID 000499742000037

• Reversible and selective ion intercalation through the top surface of few-layer MoS2. Nature communications Zhang, J., Yang, A., Wu, X., van de Groep, J., Tang, P., Li, S., Liu, B., Shi, F., Wan, J., Li, Q., Sun, Y., Lu, Z., Zheng, X., Zhou, G., Wu, C., Zhang, S., Brongersma, M. L., Li, J., Cui, Y. 2018; 9 (1): 5289

  Abstract

  Electrochemical intercalation of ions into the van der Waals gap of two-dimensional (2D) layered materials is a promising low-temperature synthesis strategy to tune their physical and chemical properties. It is widely believed that ions prefer intercalation into the van der Waals gap through the edges of the 2D flake, which generally causes wrinkling and distortion. Here we demonstrate that the ions can also intercalate through the top surface of few-layer MoS2 and this type of intercalation is more reversible and stable compared to the intercalation through the edges. Density functional theory calculations show that this intercalation is enabled by the existence of natural defects in exfoliated MoS2 flakes. Furthermore, we reveal that sealed-edge MoS2 allows intercalation of small alkali metal ions (e.g., Li+ and Na+) and rejects large ions (e.g., K+). These findings imply potential applications in developing functional 2D-material-based devices with high tunability and ion selectivity.

  View details for PubMedID 30538249

• Order and Disorder Embedded in a Spectrally Interleaved Metasurface ACS PHOTONICS Yannai, M., Maguid, E., Faerman, A., Li, Q., Song, J., Kleiner, V., Brongersma, M. L., Hasman, E. 2018; 5 (12): 4764–68

  View details for DOI 10.1021/acsphotonics.8b01138

  View details for Web of Science ID 000454463000007

• Spectrally interleaved topologies using geometric phase metasurfaces OPTICS EXPRESS Yannai, M., Maguid, E., Faerman, A., Li, Q., Song, J., Kleiner, V., Brongersma, M. L., Hasman, E. 2018; 26 (23): 31031–38

  Abstract

  Metasurfaces facilitate the interleaving of multiple topologies in an ultra-thin photonic system. Here, we report on the spectral interleaving of topological states of light using a geometric phase metasurface. We realize that a dielectric spectrally interleaved metasurface generates multiple interleaved vortex beams at different wavelengths. By harnessing the space-variant polarization manipulations that are enabled by the geometric phase mechanism, a vectorial vortex array is implemented. The presented interleaved topologies concept can greatly enhance the functionality of advanced microscopy and communication systems.

  View details for DOI 10.1364/OE.26.031031

  View details for Web of Science ID 000449972600116

  View details for PubMedID 30469990