Stanford Advisors


All Publications


  • Ultralow-Overpotential Acidic Oxygen Evolution Reaction Over Bismuth Telluride-Carbon Nanotube Heterostructure with Organic Framework. Small (Weinheim an der Bergstrasse, Germany) Arbab, A. A., Cho, S., Jung, E., Han, H. S., Park, S., Lee, H. 2023: e2307059

    Abstract

    The state-of-the-art iridium and ruthenium oxides-based materials are best known for high efficiency and stability in acidic oxygen evolution reaction (OER). However, the development of economically feasible catalysts for water-splitting technologies is challenging by the requirements of low overpotential, high stability, and resistance of catalysts to dissolution during the acidic oxygen evolution reaction . Herein, an organometallic core-shell heterostructure composed of a carbon nanotube core (CNT) and bismuth telluride (Bi2 Te3 ) shell (denoted as nC-Bi2 Te3 ) is designed and use it as a catalyst for the acidic OER. The proposed catalyst achieves an ultralow overpotential of 160 mV at 10 mA cm-2 (geometrical), thereby outperforming most of the state-of-the-art precious-metal-based catalysts. The low Tafel slope of 30 mV dec-1 and charge transfer resistance (RCT ) of 1.5 Ω demonstrate its excellent electrocatalytic activity. The morphological and chemical compositions of nC-Bi2 Te3 enable the generation of ─OH functional group in the Bi─Te sections formed via a ligand support, which enhances the absorption capacity of H+ ions and increases the intrinsic catalytic activity. The presented insights regarding the material composition-structure relationship can help expand the application scope of high-performance catalysts.

    View details for DOI 10.1002/smll.202307059

    View details for PubMedID 37946687

  • Local Structure of Sulfur Vacancies on the Basal Plane of Monolayer MoS2. ACS nano Garcia-Esparza, A. T., Park, S., Abroshan, H., Paredes Mellone, O. A., Vinson, J., Abraham, B., Kim, T. R., Nordlund, D., Gallo, A., Alonso-Mori, R., Zheng, X., Sokaras, D. 2022

    Abstract

    The nature of the S-vacancy is central to controlling the electronic properties of monolayer MoS2. Understanding the geometric and electronic structures of the S-vacancy on the basal plane of monolayer MoS2 remains elusive. Here, operando S K-edge X-ray absorption spectroscopy shows the formation of clustered S-vacancies on the basal plane of monolayer MoS2 under reaction conditions (H2 atmosphere, 100-600 °C). First-principles calculations predict spectral fingerprints consistent with the experimental results. The Mo K-edge extended X-ray absorption fine structure shows the local structure as coordinatively unsaturated Mo with 4.1 ± 0.4 S atoms as nearest neighbors (above 400 °C in an H2 atmosphere). Conversely, the 6-fold Mo-Mo coordination in the crystal remains unchanged. Electrochemistry confirms similar active sites for hydrogen evolution. The identity of the S-vacancy defect on the basal plane of monolayer MoS2 is herein elucidated for applications in optoelectronics and catalysis.

    View details for DOI 10.1021/acsnano.2c01388

    View details for PubMedID 35380038

  • Operando Study of Thermal Oxidation of Monolayer MoS2. Advanced science (Weinheim, Baden-Wurttemberg, Germany) Park, S., Garcia-Esparza, A. T., Abroshan, H., Abraham, B., Vinson, J., Gallo, A., Nordlund, D., Park, J., Kim, T. R., Vallez, L., Alonso-Mori, R., Sokaras, D., Zheng, X. 2021; 8 (9): 2002768

    Abstract

    Monolayer MoS2 is a promising semiconductor to overcome the physical dimension limits of microelectronic devices. Understanding the thermochemical stability of MoS2 is essential since these devices generate heat and are susceptible to oxidative environments. Herein, the promoting effect of molybdenum oxides (MoO x ) particles on the thermal oxidation of MoS2 monolayers is shown by employing operando X-ray absorption spectroscopy, ex situ scanning electron microscopy and X-ray photoelectron spectroscopy. The study demonstrates that chemical vapor deposition-grown MoS2 monolayers contain intrinsic MoO x and are quickly oxidized at 100 °C (3 vol% O2/He), in contrast to previously reported oxidation thresholds (e.g., 250 °C, t ≤ 1 h in the air). Otherwise, removing MoO x increases the thermal oxidation onset temperature of monolayer MoS2 to 300 °C. These results indicate that MoO x promote oxidation. An oxide-free lattice is critical to the long-term stability of monolayer MoS2 in state-of-the-art 2D electronic, optical, and catalytic applications.

    View details for DOI 10.1002/advs.202002768

    View details for PubMedID 33977043

    View details for PubMedCentralID PMC8097340

  • Operando Study of Thermal Oxidation of Monolayer MoS2 ADVANCED SCIENCE Park, S., Garcia-Esparza, A. T., Abroshan, H., Abraham, B., Vinson, J., Gallo, A., Nordlund, D., Park, J., Kim, T., Vallez, L., Alonso-Mori, R., Sokaras, D., Zheng, X. 2021
  • Effect of Adventitious Carbon on Pit Formation of Monolayer MoS2. Advanced materials (Deerfield Beach, Fla.) Park, S., Siahrostami, S., Park, J., Mostaghimi, A. H., Kim, T. R., Vallez, L., Gill, T. M., Park, W., Goodson, K. E., Sinclair, R., Zheng, X. 2020: e2003020

    Abstract

    Forming pits on molybdenum disulfide (MoS2 ) monolayers is desirable for (opto)electrical, catalytic, and biological applications. Thermal oxidation is a potentially scalable method to generate pits on monolayer MoS2 , and pits are assumed to preferentially form around undercoordinated sites, such as sulfur vacancies. However, studies on thermal oxidation of MoS2 monolayers have not considered the effect of adventitious carbon (C) that is ubiquitous and interacts with oxygen at elevated temperatures. Herein, the effect of adventitious C on the pit formation on MoS2 monolayers during thermal oxidation is studied. The in situ environmental transmission electron microscopy measurements herein show that pit formation is preferentially initiated at the interface between adventitious C nanoparticles and MoS2 , rather than only sulfur vacancies. Density functional theory (DFT) calculations reveal that the C/MoS2 interface favors the sequential adsorption of oxygen atoms with facile kinetics. These results illustrate the important role of adventitious C on pit formation on monolayer MoS2 .

    View details for DOI 10.1002/adma.202003020

    View details for PubMedID 32743836

  • Profitable Production of Stable Electrical Power Using Wind-battery Hybrid Power Systems: A Case Study from Mt. Taegi, South Korea INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING-GREEN TECHNOLOGY Park, S., Hang, G., Koo, J., Choi, H., Shim, J. 2019; 6 (5): 919–30
  • Profitable Production of Stable Electrical Power Using Wind-battery Hybrid Power Systems: A Case Study from Mt. Taegi, South Korea (vol 6, pg 1, 2019) INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING-GREEN TECHNOLOGY Park, S., Han, G., Koo, J., Choi, H., Shim, J. 2019; 6 (3): 667
  • Rapid Flame-Annealed CuFe2O4 as Efficient Photocathode for Photoelectrochemical Hydrogen Production ACS SUSTAINABLE CHEMISTRY & ENGINEERING Park, S., Baek, J., Zhang, L., Lee, J., Stone, K. H., Cho, I., Guo, J., Jung, H., Zheng, X. 2019; 7 (6): 5867–74
  • Selective and Efficient Gd-Doped BiVO4 Photoanode for Two-Electron Water Oxidation to H2O2 ACS ENERGY LETTERS Baek, J., Gill, T., Abroshan, H., Park, S., Shi, X., Norskoy, J., Jung, H., Siahrostami, S., Zheng, X. 2019; 4 (3): 720–28
  • Enhancing Catalytic Activity of MoS2 Basal Plane S-Vacancy by Co Cluster Addition ACS ENERGY LETTERS Park, S., Park, J., Abroshan, H., Zhang, L., Kim, J., Zhang, J., Guo, J., Siahrostami, S., Zheng, X. 2018; 3 (11): 2685–93
  • Wafer-recyclable, environment-friendly transfer printing for large-scale thin-film nanoelectronics PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Wie, D., Zhang, Y., Kim, M., Kim, B., Park, S., Kim, Y., Irazoqui, P. P., Zheng, X., Xu, B., Lee, C. 2018; 115 (31): E7236–E7244

    Abstract

    Transfer printing of thin-film nanoelectronics from their fabrication wafer commonly requires chemical etching on the sacrifice of wafer but is also limited by defects with a low yield. Here, we introduce a wafer-recyclable, environment-friendly transfer printing process that enables the wafer-scale separation of high-performance thin-film nanoelectronics from their fabrication wafer in a defect-free manner that enables multiple reuses of the wafer. The interfacial delamination is enabled through a controllable cracking phenomenon in a water environment at room temperature. The physically liberated thin-film nanoelectronics can be then pasted onto arbitrary places of interest, thereby endowing the particular surface with desirable add-on electronic features. Systematic experimental, theoretical, and computational studies reveal the underlying mechanics mechanism and guide manufacturability for the transfer printing process in terms of scalability, controllability, and reproducibility.

    View details for PubMedID 30012591

  • Ultrafast Flame Annealing of TiO2 Paste for Fabricating Dye-Sensitized and Perovskite Solar Cells with Enhanced Efficiency SMALL Kim, J., Chai, S., Cho, Y., Cai, L., Kim, S., Park, S., Park, J., Zheng, X. 2017; 13 (42)
  • Ultrafast Flame Annealing of TiO2 Paste for Fabricating Dye-Sensitized and Perovskite Solar Cells with Enhanced Efficiency. Small (Weinheim an der Bergstrasse, Germany) Kim, J. K., Chai, S. U., Cho, Y., Cai, L., Kim, S. J., Park, S., Park, J. H., Zheng, X. 2017; 13 (42)

    Abstract

    Mesoporous TiO2 nanoparticle (NP) films are broadly used as electrodes in photoelectrochemical cells, dye-sensitized solar cells (DSSCs), and perovskite solar cells (PSCs). State-of-the-art mesoporous TiO2 NP films for these solar cells are fabricated by annealing TiO2 paste-coated fluorine-doped tin oxide glass in a box furnace at 500 °C for ≈30 min. Here, the use of a nontraditional reactor, i.e., flame, is reported for the high throughput and ultrafast annealing of TiO2 paste (≈1 min). This flame-annealing method, compared to conventional furnace annealing, exhibits three distinct benefits. First, flame removes polymeric binders in the initial TiO2 paste more completely because of its high temperature (≈1000 °C). Second, flame induces strong interconnections between TiO2 nanoparticles without affecting the underlying transparent conducting oxide substrate. Third, the flame-induced carbothermic reduction on the TiO2 surface facilitates charge injection from the dye/perovskite to TiO2 . Consequently, when the flame-annealed mesoporous TiO2 film is used to fabricate DSSCs and PSCs, both exhibit enhanced charge transport and higher power conversion efficiencies than those fabricated using furnace-annealed TiO2 films. Finally, when the ultrafast flame-annealing method is combined with a fast dye-coating method to fabricate DSSC devices, its total fabrication time is reduced from over 3 h to ≈10 min.

    View details for DOI 10.1002/smll.201702260

    View details for PubMedID 28940949

  • for hydrogen evolution. Nature communications Tsai, C., Li, H., Park, S., Park, J., Han, H. S., Nørskov, J. K., Zheng, X., Abild-Pedersen, F. 2017; 8: 15113-?

    Abstract

    Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS2 catalysts. However, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduce a scalable route towards generating S-vacancies on the MoS2 basal plane using electrochemical desulfurization. Even though sulfur atoms on the basal plane are known to be stable and inert, we find that they can be electrochemically reduced under accessible applied potentials. This can be done on various 2H-MoS2 nanostructures. By changing the applied desulfurization potential, the extent of desulfurization and the resulting activity can be varied. The resulting active sites are stable under extended desulfurization durations and show consistent HER activity.

    View details for DOI 10.1038/ncomms15113

    View details for PubMedID 28429782

  • Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution NATURE COMMUNICATIONS Tsai, C., Li, H., Park, S., Park, J., Han, H. S., Norskov, J. K., Zheng, X., Abild-Pedersen, F. 2017; 8

    Abstract

    Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS2 catalysts. However, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduce a scalable route towards generating S-vacancies on the MoS2 basal plane using electrochemical desulfurization. Even though sulfur atoms on the basal plane are known to be stable and inert, we find that they can be electrochemically reduced under accessible applied potentials. This can be done on various 2H-MoS2 nanostructures. By changing the applied desulfurization potential, the extent of desulfurization and the resulting activity can be varied. The resulting active sites are stable under extended desulfurization durations and show consistent HER activity.

    View details for DOI 10.1038/ncomms15113

    View details for Web of Science ID 000399985300001

  • Molybdenum disulfide catalyzed tungsten oxide for on-chip acetone sensing APPLIED PHYSICS LETTERS Li, H., Ahn, S. H., Park, S., Cai, L., Zhao, J., He, J., Zhou, M., Park, J., Zheng, X. 2016; 109 (13)

    View details for DOI 10.1063/1.4962946

    View details for Web of Science ID 000384747900042