Academic Appointments


  • Associate Professor, Geological Sciences
  • Associate Professor, Photon Science Directorate
  • Associate Professor (By courtesy), Geophysics

Administrative Appointments


  • Associate Professor, Stanford University (2014 - Present)
  • Assistant Professor, Stanford University (2007 - 2014)
  • Assistant Professor of Geophysics (by courtesy), Stanford University (2009 - Present)
  • Adjunct Professor, Zhejiang University (2009 - Present)
  • J. R. Oppenheimer Post-doctoral Fellow, Los Alamos National Laboratory (2005 - 2007)

Honors & Awards


  • Award Recipient, Mineralogical Society of America (2013)
  • NSF CAREER Award, National Science Foundation (2011)
  • Fellow, Frederick E. Terman Fellowship (2009 - Present)
  • COMPRES Distinguished Lecturer, Stanford University (2008-2009)
  • Rosalind Franklin Young Investigator Award, University of Chicago (2006)
  • Mineral and Rocks Physics Group Student Research Award, University of Chicago (2006)
  • Fellow, J. R. Oppenheimer Fellowship (2005 - 2007)
  • Phi Beta Kappa, Massachusetts Institute of Technology (1998)

Boards, Advisory Committees, Professional Organizations


  • Advisory Group on Women at SLAC, SLAC National Accelerator Laboratory (2015 - Present)
  • CSEDI Steering Committee, NSF (2015 - Present)
  • Chair, GES Graduate Admissions Committee, Stanford University (2015 - Present)
  • DIF Advisory Committee, Stanford University (2015 - Present)
  • GES Communications Committee, Stanford University (2014 - Present)
  • Co-chair of Extreme Physics and Chemistry Directorate, Deep Carbon Observatory (2013 - Present)
  • GES Graduate Admissions Committee, Stanford University (2012 - Present)
  • Scientific Steering Committee for the Extreme Physics and Chemistry Directorate, Deep Carbon Observatory (2011 - Present)
  • Associate Editor, American Mineralogist (2010 - Present)
  • GES representative on SES Educational Outreach Committee, Stanford University (2010 - Present)
  • Pre-Majors Advisor, Stanford University (2010 - Present)
  • SNAP Instrument Design Team - Spallation Neutron Source, ORNL, Oak Ridge National Laboratory (2010 - Present)
  • COMPRES Facilities Committee, Consortium for Materials Properties Research in Earth Sciences (2009 - Present)
  • Member of APS Users Organization Steering Committee, Advanced Photon Source, Argonne National Laboratory (2009 - Present)
  • West Coast High Pressure Facilities Review Committee, Advanced Light Source, Lawrence Berkeley National Laboratory (2006 - Present)
  • Photon Science Integration Committee, SLAC National Accelerator Laboratory (2012 - 2013)
  • LCLS Users' Executive Committee, SLAC National Accelerator Laboratory (2011 - 2014)
  • Chair, Award Committee, Rosalind Frankin Young Investigator Asard (2010 - 2010)
  • GES Dept Seminar Coordinator (w/ Maher), Stanford University (2009 - 2011)
  • Search Committee for Geochronology, Petrology, Geodynamics position, Stanford University (2008 - 2009)
  • GES Long Range Planning Committee, Stanford University (2007 - 2008)

Professional Education


  • Ph.D., University of Chicago, Geophysical Sciences (2005)
  • B.S., Massachusetts Institute of Technology, Materials Science and Engineering (1998)

Current Research and Scholarly Interests


Research
Pressure induces dramatic changes in materials. I study the behavior of materials under compression which often leads to the discovery of novel phases and new phenomena. This research has a wide variety of applications including improving our understanding the interiors of Earth and other planetary bodies, providing insight into the condensation and evolution of volatiles in planetary systems, and providing guidance for developing new materials for energy related applications like hydrogen fuel storage and advanced batteries.

Teaching
I teach classes on understanding the Earth's interior, mineralogy, and a freshman seminar on diamonds.

2014-15 Courses


Postdoctoral Advisees


All Publications


  • Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu-Cl Hybrid Perovskite. Journal of the American Chemical Society Jaffe, A., Lin, Y., Mao, W. L., Karunadasa, H. I. 2015; 137 (4): 1673-1678

    Abstract

    Pressure-induced changes in the electronic structure of two-dimensional Cu-based materials have been a subject of intense study. In particular, the possibility of suppressing the Jahn-Teller distortion of d(9) Cu centers with applied pressure has been debated over a number of decades. We studied the structural and electronic changes resulting from the application of pressures up to ca. 60 GPa on a two-dimensional copper(II)-chloride perovskite using diamond anvil cells (DACs), through a combination of in situ powder X-ray diffraction, electronic absorption and vibrational spectroscopy, dc resistivity measurements, and optical observations. Our measurements show that compression of this charge-transfer insulator initially yields a first-order structural phase transition at ca. 4 GPa similar to previous reports on other Cu(II)-Cl perovskites, during which the originally translucent yellow solid turns red. Further compression induces a previously unreported phase transition at ca. 8 GPa and dramatic piezochromism from translucent red-orange to opaque black. Two-probe dc resistivity measurements conducted within the DAC show the first instance of appreciable conductivity in Cu(II)-Cl perovskites. The conductivity increases by 5 orders of magnitude between 7 and 50 GPa, with a maximum measured conductivity of 2.9 × 10(-4) S·cm(-1) at 51.4 GPa. Electronic absorption spectroscopy and variable-temperature conductivity measurements indicate that the perovskite behaves as a 1.0 eV band-gap semiconductor at 39.7 GPa and has an activation energy for electronic conduction of 0.232(1) eV at 40.2 GPa. Remarkably, all these changes are reversible: the material reverts to a translucent yellow solid upon decompression, and ambient pressure powder X-ray diffraction data taken before and after compression up to 60 GPa show that the original structure is maintained with minimal hysteresis.

    View details for DOI 10.1021/ja512396m

    View details for PubMedID 25580620

  • Tetrahedrally coordinated carbonates in Earth's lower mantle. Nature communications Boulard, E., Pan, D., Galli, G., Liu, Z., Mao, W. L. 2015; 6: 6311-?

    Abstract

    Carbonates are the main species that bring carbon deep into our planet through subduction. They are an important rock-forming mineral group, fundamentally distinct from silicates in the Earth's crust in that carbon binds to three oxygen atoms, while silicon is bonded to four oxygens. Here we present experimental evidence that under the sufficiently high pressures and high temperatures existing in the lower mantle, ferromagnesian carbonates transform to a phase with tetrahedrally coordinated carbons. Above 80 GPa, in situ synchrotron infrared experiments show the unequivocal spectroscopic signature of the high-pressure phase of (Mg,Fe)CO3. Using ab-initio calculations, we assign the new infrared signature to C-O bands associated with tetrahedrally coordinated carbon with asymmetric C-O bonds. Tetrahedrally coordinated carbonates are expected to exhibit substantially different reactivity than low-pressure threefold coordinated carbonates, as well as different chemical properties in the liquid state. Hence, this may have significant implications for carbon reservoirs and fluxes, and the global geodynamic carbon cycle.

    View details for DOI 10.1038/ncomms7311

    View details for PubMedID 25692448

  • Strain-induced modification of optical selection rules in lanthanide-based upconverting nanoparticles Nano Letters Wisser, M., Chea, M., Lin, Y., Wu, D., Mao, W. L., Salleo, A., Dionne, J. 2015

    View details for DOI 10.1021/nl504738k

  • Compressed hydrogen heats up Nature Materials Mao, W. L. 2015

    View details for DOI 10.1038/nmat4245

  • High-pressure storage of hydrogen fuel: ammonia borane and its related compounds CHINESE SCIENCE BULLETIN Lin, Y., Mao, W. L. 2014; 59 (36): 5235-5240
  • Deviatoric stress-induced phase transitions in diamantane JOURNAL OF CHEMICAL PHYSICS Yang, F., Lin, Y., Dahl, J. E., Carlson, R. M., Mao, W. L. 2014; 141 (15)

    View details for DOI 10.1063/1.4897252

    View details for Web of Science ID 000344346000022

  • Bandgap closure and reopening in CsAuI3 at high pressure PHYSICAL REVIEW B Wang, S., Kemper, A. F., Baldini, M., SHAPIRO, M. C., Riggs, S. C., Zhao, Z., Liu, Z., Devereaux, T. P., Geballe, T. H., Fisher, I. R., Mao, W. L. 2014; 89 (24)
  • Pressure induced second-order structural transition in Sr3Ir2O7 JOURNAL OF PHYSICS-CONDENSED MATTER Zhao, Z., Wang, S., Qi, T. F., Zeng, Q., Hirai, S., Kong, P. P., Li, L., PARK, C., Yuan, S. J., Jin, C. Q., Cao, G., Mao, W. L. 2014; 26 (21)
  • Disproportionation of (Mg,Fe)SiO3 perovskite in Earth's deep lower mantle SCIENCE Zhang, L., Meng, Y., Yang, W., Wang, L., Mao, W. L., Zeng, Q., Jeong, J. S., Wagner, A. J., Mkhoyan, K. A., Liu, W., Xu, R., Mao, H. 2014; 344 (6186): 877-882

    Abstract

    The mineralogical constitution of the Earth's mantle dictates the geophysical and geochemical properties of this region. Previous models of a perovskite-dominant lower mantle have been built on the assumption that the entire lower mantle down to the top of the D″ layer contains ferromagnesian silicate [(Mg,Fe)SiO3] with nominally 10 mole percent Fe. On the basis of experiments in laser-heated diamond anvil cells, at pressures of 95 to 101 gigapascals and temperatures of 2200 to 2400 kelvin, we found that such perovskite is unstable; it loses its Fe and disproportionates to a nearly Fe-free MgSiO3 perovskite phase and an Fe-rich phase with a hexagonal structure. This observation has implications for enigmatic seismic features beyond ~2000 kilometers depth and suggests that the lower mantle may contain previously unidentified major phases.

    View details for DOI 10.1126/science.1250274

    View details for Web of Science ID 000336233800041

  • Tuning the crystal structure and electronic states of Ag2Se: Structural transitions and metallization under pressure PHYSICAL REVIEW B Zhao, Z., Wang, S., Oganov, A. R., Chen, P., Liu, Z., Mao, W. L. 2014; 89 (18)
  • Universal fractional noncubic power law for density of metallic glasses. Physical review letters Zeng, Q., Kono, Y., Lin, Y., Zeng, Z., Wang, J., Sinogeikin, S. V., Park, C., Meng, Y., Yang, W., Mao, H., Mao, W. L. 2014; 112 (18): 185502-?

    Abstract

    As a fundamental property of a material, density is controlled by the interatomic distances and the packing of microscopic constituents. The most prominent atomistic feature in a metallic glass (MG) that can be measured is its principal diffraction peak position (q_{1}) observable by x-ray, electron, or neutron diffraction, which is closely associated with the average interatomic distance in the first shell. Density (and volume) would naturally be expected to vary under compression in proportion to the cube of the one-dimensional interatomic distance. However, by using high pressure as a clean tuning parameter and high-resolution in situ techniques developed specifically for probing the density of amorphous materials, we surprisingly found that the density of a MG varies with the 5/2 power of q_{1}, instead of the expected cubic relationship. Further studies of MGs of different compositions repeatedly produced the same fractional power law of 5/2 in all three MGs we investigated, suggesting a universal feature in MG.

    View details for PubMedID 24856706

  • High Pressure Raman and X-ray Diffraction Study of [121] Tetramantane JOURNAL OF PHYSICAL CHEMISTRY C Yang, F., Lin, Y., Dahl, J. E., Carlson, R. M., Mao, W. L. 2014; 118 (14): 7683-7689

    View details for DOI 10.1021/jp500431k

    View details for Web of Science ID 000334571700050

  • Phase transitions in metastable phases of silicon JOURNAL OF APPLIED PHYSICS Zeng, Z., Zeng, Q., Mao, W. L., Qu, S. 2014; 115 (10)

    View details for DOI 10.1063/1.4868156

    View details for Web of Science ID 000333083100023

  • Strain derivatives of T-c in HgBa2CuO4+delta: The CuO2 plane alone is not enough PHYSICAL REVIEW B Wang, S., Zhang, J., Yan, J., Chen, X., Struzhkin, V., Tabis, W., Barisic, N., Chan, M. K., Dorow, C., Zhao, X., Greven, M., Mao, W. L., Geballe, T. 2014; 89 (2)
  • Five-dimensional visualization of phase transition in BiNiO3 under high pressure APPLIED PHYSICS LETTERS Liu, Y., Wang, J., Azuma, M., Mao, W. L., Yang, W. 2014; 104 (4)

    View details for DOI 10.1063/1.4863229

    View details for Web of Science ID 000331209900069

  • Evidence for photo-induced monoclinic metallic VO2 under high pressure APPLIED PHYSICS LETTERS Hsieh, W., Trigo, M., Reis, D. A., Artioli, G. A., Malavasi, L., Mao, W. L. 2014; 104 (2)

    View details for DOI 10.1063/1.4862197

    View details for Web of Science ID 000330431000045

  • Pressure-induced densification in GeO2 glass: A transmission x-ray microscopy study APPLIED PHYSICS LETTERS Lin, Y., Zeng, Q., Yang, W., Mao, W. L. 2013; 103 (26)

    View details for DOI 10.1063/1.4860993

    View details for Web of Science ID 000329977400027

  • Elastic moduli of polycrystalline Li15Si4 produced in lithium ion batteries JOURNAL OF POWER SOURCES Zeng, Z., Liu, N., Zeng, Q., Ding, Y., Qu, S., Cui, Y., Mao, W. L. 2013; 242: 732-735
  • High-pressure Raman spectroscopy of phase change materials APPLIED PHYSICS LETTERS Hsieh, W., Zalden, P., Wuttig, M., Lindenberg, A. M., Mao, W. L. 2013; 103 (19)

    View details for DOI 10.1063/1.4829358

    View details for Web of Science ID 000327817000029

  • Formation of an interconnected network of iron melt at Earth's lower mantle conditions NATURE GEOSCIENCE Shi, C. Y., Zhang, L., Yang, W., Liu, Y., Wang, J., Meng, Y., Andrews, J. C., Mao, W. L. 2013; 6 (11): 971-975

    View details for DOI 10.1038/NGEO1956

    View details for Web of Science ID 000326505800023

  • Nanoscale Elemental Sensitivity Study of Nd2Fe14B Using Absorption Correlation Tomography MICROSCOPY RESEARCH AND TECHNIQUE Kao, T. L., Shi, C. Y., Wang, J., Mao, W. L., Liu, Y., Yang, W. 2013; 76 (11): 1112-1117

    Abstract

    Transmission X-ray microscopy (TXM) is a rapidly developing technique with the capability of nanoscale three dimensional (3D) real-space imaging. Combined with the wide range in energy tunability from synchrotron sources, TXM enables the retrieval of 3D microstructural information with elemental/chemical sensitivity that would otherwise be inaccessible. The differential absorption contrast above and below absorption edges has been used to reconstruct the distributions of different elements, assuming the absorption edges of the interested elements are fairly well separated. Here we present an "Absorption Correlation Tomography" (ACT) method based on the correlation of the material absorption across multiple edges. ACT overcomes the significant limitation caused by overlapping absorption edges, significantly expands the capabilities of TXM, and makes it possible for fully quantitative nano-scale 3D structural investigation with chemical/elemental sensitivity. The capability and robustness of this new methodology is demonstrated in a case study of an important type of rare earth magnet (Nd₂Fe₁₄B).

    View details for DOI 10.1002/jemt.22273

    View details for Web of Science ID 000326023800003

    View details for PubMedID 23922210

  • Bonding and electronic changes in rhodochrosite at high pressure AMERICAN MINERALOGIST Farfan, G. A., Boulard, E., Wang, S., Mao, W. L. 2013; 98 (10): 1817-1823
  • Symmetrization driven spin transition in epsilon-FeOOH at high pressure EARTH AND PLANETARY SCIENCE LETTERS Gleason, A. E., Quiroga, C. E., Suzuki, A., Pentcheva, R., Mao, W. L. 2013; 379: 49-55
  • Pressure-induced structural transitions and metallization in Ag2Te PHYSICAL REVIEW B Zhao, Z., Wang, S., Zhang, H., Mao, W. L. 2013; 88 (2)
  • Strength of iron at core pressures and evidence for a weak Earth's inner core NATURE GEOSCIENCE Gleason, A. E., Mao, W. L. 2013; 6 (7): 571-574

    View details for DOI 10.1038/NGEO1808

    View details for Web of Science ID 000321002700022

  • Sound velocities for hexagonally close-packed iron compressed hydrostatically to 136GPa from phonon density of states GEOPHYSICAL RESEARCH LETTERS Gleason, A. E., Mao, W. L., Zhao, J. Y. 2013; 40 (12): 2983-2987

    View details for DOI 10.1002/grl.50588

    View details for Web of Science ID 000321951300019

  • Elastic and inelastic behavior of graphitic C3N4 under high pressure CHEMICAL PHYSICS LETTERS Jia, R., Amulele, G., Zinin, P. V., Odake, S., Eng, P., Khabashesku, V., Mao, W. L., Ming, L. C. 2013; 575: 67-70
  • Three-Dimensional Coherent X-Ray Diffraction Imaging of Molten Iron in Mantle Olivine at Nanoscale Resolution PHYSICAL REVIEW LETTERS Jiang, H., Xu, R., Chen, C., Yang, W., Fan, J., Tao, X., Song, C., Kohmura, Y., Xiao, T., Wang, Y., Fei, Y., Ishikawa, T., Mao, W. L., Miao, J. 2013; 110 (20)
  • The effect of composition on pressure-induced devitrification in metallic glasses APPLIED PHYSICS LETTERS Zeng, Q., Mao, W. L., Sheng, H., Zeng, Z., Hu, Q., Meng, Y., Lou, H., Peng, F., Yang, W., Sinogeikin, S. V., Jiang, J. 2013; 102 (17)

    View details for DOI 10.1063/1.4803539

    View details for Web of Science ID 000318553000021

  • Single-crystal structure determination of (Mg,Fe)SiO3 postperovskite PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Zhang, L., Meng, Y., Dera, P., Yang, W., Mao, W. L., Mao, H. 2013; 110 (16): 6292-6295

    Abstract

    Knowledge of the structural properties of mantle phases is critical for understanding the enigmatic seismic features observed in the Earth's lower mantle down to the core-mantle boundary. However, our knowledge of lower mantle phase equilibria at high pressure (P) and temperature (T) conditions has been based on limited information provided by powder X-ray diffraction technique and theoretical calculations. Here, we report the in situ single-crystal structure determination of (Mg,Fe)SiO3 postperovskite (ppv) at high P and after temperature quenching in a diamond anvil cell. Using a newly developed multigrain single-crystal X-ray diffraction analysis technique in a diamond anvil cell, crystallographic orientations of over 100 crystallites were simultaneously determined at high P in a coarse-grained polycrystalline sample containing submicron ppv grains. Conventional single-crystal structural analysis and refinement methods were applied for a few selected ppv crystallites, which demonstrate the feasibility of the in situ study of crystal structures of submicron crystallites in a multiphase polycrystalline sample contained within a high P device. The similarity of structural models for single-crystal Fe-bearing ppv (~10 mol% Fe) and Fe-free ppv from previous theoretical calculations suggests that the Fe content in the mantle has a negligible effect on the crystal structure of the ppv phase.

    View details for DOI 10.1073/pnas.1304402110

    View details for Web of Science ID 000318041500023

    View details for PubMedID 23576761

  • Pressure-induced symmetry breaking in tetragonal CsAuI3 PHYSICAL REVIEW B Wang, S., Hirai, S., Shapiro, M. C., Riggs, S. C., Geballe, T. H., Mao, W. L., Fisher, I. R. 2013; 87 (5)
  • Pressure-induced tetragonal-orthorhombic phase transitions in CeRuPO APPLIED PHYSICS LETTERS Hirai, S., Kamihara, Y., Wakatsuki, A., Matoba, M., Mao, W. L. 2013; 102 (5)

    View details for DOI 10.1063/1.4791690

    View details for Web of Science ID 000314770300040

  • Novel pressure-induced phase transitions in Co3O4 APPLIED PHYSICS LETTERS Hirai, S., Mao, W. L. 2013; 102 (4)

    View details for DOI 10.1063/1.4790387

    View details for Web of Science ID 000314723600034

  • Giant atomic displacement at a magnetic phase transition in metastable Mn3O4 PHYSICAL REVIEW B Hirai, S., dos Santos, A. M., SHAPIRO, M. C., Molaison, J. J., Pradhan, N., Guthrie, M., Tulk, C. A., Fisher, I. R., Mao, W. L. 2013; 87 (1)
  • Nanoprobes for Deep Carbon CARBON IN EARTH Mao, W. L., Boulard, E. 2013; 75: 423-448
  • Lithographically fabricated gratings for the interferometric measurement of material shear moduli under extreme conditions JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B Gleason, A. E., Tiberio, R. C., Mao, W. L., Ali, S., Bolme, C. A., Lazicki, A., Bordonaro, G., Treichler, J., Genova, V., Eggert, J. H. 2012; 30 (6)

    View details for DOI 10.1116/1.4767323

    View details for Web of Science ID 000311667300011

  • Pressure-induced tuning of a magnetic phase separation in Nd0.53Sr0.47MnO3 PHYSICAL REVIEW B Baldini, M., Ding, Y., Wang, S., Lin, Y., Tulk, C. A., dos Santos, A. M., Mitchell, J. F., Haskel, D., Mao, W. L. 2012; 86 (9)
  • Long-Range Ordered Carbon Clusters: A Crystalline Material with Amorphous Building Blocks SCIENCE Wang, L., Liu, B., Li, H., Yang, W., Ding, Y., Sinogeikin, S. V., Meng, Y., Liu, Z., Zeng, X. C., Mao, W. L. 2012; 337 (6096): 825-828

    Abstract

    Solid-state materials can be categorized by their structures into crystalline (having periodic translation symmetry), amorphous (no periodic and orientational symmetry), and quasi-crystalline (having orientational but not periodic translation symmetry) phases. Hybridization of crystalline and amorphous structures at the atomic level has not been experimentally observed. We report the discovery of a long-range ordered material constructed from units of amorphous carbon clusters that was synthesized by compressing solvated fullerenes. Using x-ray diffraction, Raman spectroscopy, and quantum molecular dynamics simulation, we observed that, although carbon-60 cages were crushed and became amorphous, the solvent molecules remained intact, playing a crucial role in maintaining the long-range periodicity. Once formed, the high-pressure phase is quenchable back to ambient conditions and is ultra-incompressible, with the ability to indent diamond.

    View details for DOI 10.1126/science.1220522

    View details for Web of Science ID 000307535600038

    View details for PubMedID 22904007

  • Bonding and structural changes in siderite at high pressure AMERICAN MINERALOGIST Farfan, G., Wang, S., Ma, H., Caracas, R., Mao, W. L. 2012; 97 (8-9): 1421-1426
  • Families of Superhard Crystalline Carbon Allotropes Constructed via Cold Compression of Graphite and Nanotubes PHYSICAL REVIEW LETTERS Niu, H., Chen, X., Wang, S., Li, D., Mao, W. L., Li, Y. 2012; 108 (13)

    Abstract

    We report a general scheme to systematically construct two classes of structural families of superhard sp(3) carbon allotropes of cold-compressed graphite through the topological analysis of odd 5+7 or even 4+8 membered carbon rings stemmed from the stacking of zigzag and armchair chains. Our results show that the previously proposed M, bct-C(4), W and Z allotropes belong to our currently proposed families and that depending on the topological arrangement of the native carbon rings numerous other members are found that can help us understand the structural phase transformation of cold-compressed graphite and carbon nanotubes (CNTs). In particular, we predict the existence of two simple allotropes, R and P carbon, which match well the experimental x-ray diffraction patterns of cold-compressed graphite and CNTs, respectively, display a transparent wide-gap insulator ground state and possess a large Vickers hardness comparable to diamond.

    View details for DOI 10.1103/PhysRevLett.108.135501

    View details for Web of Science ID 000302019600007

    View details for PubMedID 22540712

  • Ultrafast pump-probe measurements of short small-polaron lifetimes in the mixed-valence perovskite Cs2Au2I6 under high pressures PHYSICAL REVIEW B Trigo, M., Chen, J., Jiang, M. P., Mao, W. L., Riggs, S. C., SHAPIRO, M. C., Fisher, I. R., Reis, D. A. 2012; 85 (8)
  • Effect of pressure and composition on lattice parameters and unit-cell volume of (Fe,Mg)SiO3 post-perovskite EARTH AND PLANETARY SCIENCE LETTERS Zhang, L., Meng, Y., Mao, W. L. 2012; 317: 120-125
  • Experimental and Theoretical Studies on a High Pressure Monoclinic Phase of Ammonia Borane JOURNAL OF PHYSICAL CHEMISTRY C Lin, Y., Ma, H., Matthews, C. W., Kolb, B., Sinogeikin, S., Thonhauser, T., Mao, W. L. 2012; 116 (3): 2172-2178

    View details for DOI 10.1021/jp206726t

    View details for Web of Science ID 000299584400017

  • Crystal structures of (Mg1-x,Fe-x)SiO3 postperovskite at high pressures PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Yamanaka, T., Hirose, K., Mao, W. L., Meng, Y., Ganesh, P., Shulenburger, L., Shen, G., Hemley, R. J. 2012; 109 (4): 1035-1040

    Abstract

    X-ray diffraction experiments on postperovskite (ppv) with compositions (Mg(0.9)Fe(0.1))SiO(3) and (Mg(0.6)Fe(0.4))SiO(3) at Earth core-mantle boundary pressures reveal different crystal structures. The former adopts the CaIrO(3)-type structure with space group Cmcm, whereas the latter crystallizes in a structure with the Pmcm (Pmma) space group. The latter has a significantly higher density (? = 6.119(1) g/cm(3)) than the former (? = 5.694(8) g/cm(3)) due to both the larger amount of iron and the smaller ionic radius of Fe(2+) as a result of an electronic spin transition observed by X-ray emission spectroscopy (XES). The smaller ionic radius for low-spin compared to high-spin Fe(2+) also leads to an ordered cation distribution in the M1 and M2 crystallographic sites of the higher density ppv structure. Rietveld structure refinement indicates that approximately 70% of the total Fe(2+) in that phase occupies the M2 site. XES results indicate a loss of 70% of the unpaired electronic spins consistent with a low spin M2 site and high spin M1 site. First-principles calculations of the magnetic ordering confirm that Pmcm with a two-site model is energetically more favorable at high pressure, and predict that the ordered structure is anisotropic in its electrical and elastic properties. These results suggest that interpretations of seismic structure in the deep mantle need to treat a broader range of mineral structures than previously considered.

    View details for DOI 10.1073/pnas.1118076108

    View details for Web of Science ID 000299412600015

    View details for PubMedID 22223656

  • Nanoscale diffraction imaging of the high-pressure transition in Fe1-xO APPLIED PHYSICS LETTERS Ding, Y., Cai, Z., Hu, Q., Sheng, H., Chang, J., Hemley, R. J., Mao, W. L. 2012; 100 (4)

    View details for DOI 10.1063/1.3679117

    View details for Web of Science ID 000300064500023

  • Pressure induced stabilization of antiferromagnetic phase in Nd0.53Sr0.47MnO3 Physical Review B Baldini, M., Ding, Y., Wang, S., Lin, Y., Tulk, C. A., Santos, A. M. Dos, Haskel, D., Mao, W. L. 2012; 86
  • Effect of Compressive Strain on the Raman Modes of the Dry and Hydrated BaCe0.8Y0.2O3 Proton Conductor JOURNAL OF PHYSICAL CHEMISTRY C Chen, Q., Huang, T., Baldini, M., Hushur, A., Pomjakushin, V., Clark, S., Mao, W. L., Manghnani, M. H., Braun, A., Graule, T. 2011; 115 (48): 24021-24027

    View details for DOI 10.1021/jp208525j

    View details for Web of Science ID 000297446300047

  • Amorphous Diamond: A High-Pressure Superhard Carbon Allotrope PHYSICAL REVIEW LETTERS Lin, Y., Zhang, L., Mao, H., Chow, P., Xiao, Y., Baldini, M., Shu, J., Mao, W. L. 2011; 107 (17)

    Abstract

    Compressing glassy carbon above 40 GPa, we have observed a new carbon allotrope with a fully sp(3)-bonded amorphous structure and diamondlike strength. Synchrotron x-ray Raman spectroscopy revealed a continuous pressure-induced sp(2)-to-sp(3) bonding change, while x-ray diffraction confirmed the perseverance of noncrystallinity. The transition was reversible upon releasing pressure. Used as an indenter, the glassy carbon ball demonstrated exceptional strength by reaching 130 GPa with a confining pressure of 60 GPa. Such an extremely large stress difference of >70 GPa has never been observed in any material besides diamond, indicating the high hardness of this high-pressure carbon allotrope.

    View details for DOI 10.1103/PhysRevLett.107.175504

    View details for Web of Science ID 000296984100007

    View details for PubMedID 22107536

  • High-pressure EXAFS measurements of crystalline Ge using nanocrystalline diamond anvils PHYSICAL REVIEW B Baldini, M., Yang, W., Aquilanti, G., Zhang, L., Ding, Y., Pascarelli, S., Mao, W. L. 2011; 84 (1)
  • Application of a new composite cubic-boron nitride gasket assembly for high pressure inelastic x-ray scattering studies of carbon related materials REVIEW OF SCIENTIFIC INSTRUMENTS Wang, L., Yang, W., Xiao, Y., Liu, B., Chow, P., Shen, G., Mao, W. L., Mao, H. 2011; 82 (7)

    Abstract

    We have developed a new composite cubic-boron nitride (c-BN) gasket assembly for high pressure diamond anvil cell studies, and applied it to inelastic x-ray scattering (IXS) studies of carbon related materials in order to maintain a larger sample thickness and avoid the interference from the diamond anvils. The gap size between the two diamond anvils remained ~80 ?m at 48.0 GPa with this new composite c-BN gasket assembly. The sample can be located at the center of the gap, ~20 ?m away from the surface of both diamond anvils, which provides ample distance to separate the sample signal from the diamond anvils. The high pressure IXS of a solvated C(60) sample was studied up to 48 GPa, and a pressure induced bonding transition from sp(2) to sp(3) was observed at 27 GPa.

    View details for DOI 10.1063/1.3607994

    View details for Web of Science ID 000293498400030

    View details for PubMedID 21806194

  • Compressional, temporal, and compositional behavior of H-2-O-2 compound formed by high pressure x-ray irradiation JOURNAL OF CHEMICAL PHYSICS Kung, A., Goncharov, A. F., Zha, C. S., Eng, P., Mao, W. L. 2011; 134 (23)

    Abstract

    X-ray irradiation was found to convert H(2)O at pressures above 2 GPa into a novel molecular H(2)-O(2) compound. We used optical Raman spectroscopy to explore the behavior of x-ray irradiated H(2)O samples as a function of pressure, time, and composition. The compound was found to be stable over a period of two years, as long as high pressure conditions (>2 GPa) were maintained. The Raman shifts for the H(2) and O(2) vibrons behaved differently from pure H(2) and O(2) as pressure was increased on the compound up to 70 GPa, indicating that it remains a distinct, molecular compound. Based on spectra taken from different locations in a single sample, it appears that multiple forms of the H(2)-O(2) compound exist. The structure and composition of the starting material plays an important role in compound formation, as we found that hydrogen-filled ice clathrate C(2) (H(2))H(2)O did not undergo the same dissociation as observed in ice VII upon x-ray irradiation until pressure was increased to above 10 GPa.

    View details for DOI 10.1063/1.3599479

    View details for Web of Science ID 000291992500022

    View details for PubMedID 21702562

  • Long-Range Topological Order in Metallic Glass SCIENCE Zeng, Q., Sheng, H., Ding, Y., Wang, L., Yang, W., Jiang, J., Mao, W. L., Mao, H. 2011; 332 (6036): 1404-1406

    Abstract

    Glass lacks the long-range periodic order that characterizes a crystal. In the Ce(75)Al(25) metallic glass (MG), however, we discovered a long-range topological order corresponding to a single crystal of indefinite length. Structural examinations confirm that the MG is truly amorphous, isotropic, and unstrained, yet under 25 gigapascals hydrostatic pressures, every segment of a centimeter-length MG ribbon devitrifies independently into a face-centered cubic (fcc) crystal with the identical orientation. By using molecular dynamics simulations and synchrotron x-ray techniques, we elucidate that the mismatch between the large Ce and small Al atoms frustrates the crystallization and causes amorphization, but a long-range fcc topological order still exists. Pressure induces electronic transition in Ce, which eliminates the mismatch and manifests the topological order by the formation of a single crystal.

    View details for DOI 10.1126/science.1200324

    View details for Web of Science ID 000291689000034

    View details for PubMedID 21680837

  • Low temperature transport properties of Ce-Al metallic glasses JOURNAL OF APPLIED PHYSICS Zeng, Q. S., Rotundu, C. R., Mao, W. L., Dai, J. H., Xiao, Y. M., Chow, P., Chen, X. J., Qin, C. L., Mao, H., Jiang, J. Z. 2011; 109 (11)

    View details for DOI 10.1063/1.3587453

    View details for Web of Science ID 000292214700078

  • Compressional Behavior of Bulk and Nanorod LiMn2O4 under Nonhydrostatic Stress JOURNAL OF PHYSICAL CHEMISTRY C Lin, Y., Yang, Y., Ma, H., Cui, Y., Mao, W. L. 2011; 115 (20): 9844-9849

    View details for DOI 10.1021/jp112289h

    View details for Web of Science ID 000290652200003

  • Studying single nanocrystals under high pressure using an x-ray nanoprobe REVIEW OF SCIENTIFIC INSTRUMENTS Wang, L., Ding, Y., Patel, U., Yang, W., Xiao, Z., Cai, Z., Mao, W. L., Mao, H. 2011; 82 (4)

    Abstract

    In this report, we demonstrate the feasibility of applying a 250-nm focused x-ray beam to study a single crystalline NbSe(3) nanobelt under high-pressure conditions in a diamond anvil cell. With such a small probe, we not only resolved the distribution and morphology of each individual nanobelt in the x-ray fluorescence maps but also obtained the diffraction patterns from individual crystalline nanobelts with thicknesses of less than 50 nm. Single crystalline diffraction measurements on NbSe(3) nanobelts were performed at pressures up to 20 GPa.

    View details for DOI 10.1063/1.3584881

    View details for Web of Science ID 000290051500034

    View details for PubMedID 21529021

  • Persistence of Jahn-Teller Distortion up to the Insulator to Metal Transition in LaMnO3 PHYSICAL REVIEW LETTERS Baldini, M., Struzhkin, V. V., Goncharov, A. F., Postorino, P., Mao, W. L. 2011; 106 (6)

    Abstract

    High pressure, low temperature Raman measurements performed on LaMnO3 up to 34 GPa provide the first experimental evidence for the persistence of the Jahn-Teller distortion over the entire stability range of the insulating phase. This result resolves the ongoing debate about the nature of the pressure driven insulator to metal transition (IMT), demonstrating that LaMnO3 is not a classical Mott insulator. The formation of domains of distorted and regular octahedra, observed from 3 to 34 GPa, sheds new light on the mechanism behind the IMT suggesting that LaMnO3 becomes metallic when the fraction of undistorted octahedra domains increases beyond a critical threshold.

    View details for DOI 10.1103/PhysRevLett.106.066402

    View details for Web of Science ID 000287357100016

    View details for PubMedID 21405481

  • Electronic Structure of Crystalline He-4 at High Pressures PHYSICAL REVIEW LETTERS Mao, H. K., Shirley, E. L., Ding, Y., Eng, P., Cai, Y. Q., Chow, P., Xiao, Y., Shu, J., Hemley, R. J., Kao, C., Mao, W. L. 2010; 105 (18)

    Abstract

    Using inelastic x-ray scattering techniques, we have succeeded in probing the high-pressure electronic structure of helium at 300 K. Helium has the widest known valence-conduction band gap of all materials a property whose high-pressure response has been inaccessible to direct measurements. We observed a rich electron excitation spectrum, including a cutoff edge above 23 eV, a sharp exciton peak showing linear volume dependence, and a series of excitations and continuum at 26 to 45 eV. We determined the electronic dispersion along the ?-M direction over two Brillouin zones, and provided a quantitative picture of the helium exciton beyond the simplified Wannier-Frenkel description.

    View details for DOI 10.1103/PhysRevLett.105.186404

    View details for Web of Science ID 000283652100003

    View details for PubMedID 21231121

  • High-pressure evolution of Fe2O3 electronic structure revealed by x-ray absorption PHYSICAL REVIEW B Wang, S., Mao, W. L., Sorini, A. P., Chen, C., Devereaux, T. P., Ding, Y., Xiao, Y., Chow, P., Hiraoka, N., Ishii, H., Cai, Y. Q., Kao, C. 2010; 82 (14)
  • Pressure-induced behavior of the hydrogen-dominant compound SiH4(H-2)(2) from first-principles calculations PHYSICAL REVIEW B Chen, X., Wang, S., Mao, W. L., Fu, C. L. 2010; 82 (10)
  • Size-Dependent Amorphization of Nanoscale Y2O3 at High Pressure PHYSICAL REVIEW LETTERS Wang, L., Yang, W., Ding, Y., Ren, Y., Xiao, S., Liu, B., Sinogeikin, S. V., Meng, Y., Gosztola, D. J., Shen, G., Hemley, R. J., Mao, W. L., Mao, H. 2010; 105 (9)

    Abstract

    Y2O3 with particle sizes ranging from 5 nm to 1???m were studied at high pressure using x-ray diffraction and Raman spectroscopy techniques. Nanometer-sized Y2O3 particles are shown to be more stable than their bulk counterparts, and a grain size-dependent crystalline-amorphous transition was discovered in these materials. High-energy atomic pair distribution function measurements reveal that the amorphization is associated with the breakdown of the long-rang order of the YO6 octahedra, while the nearest-neighbor edge-shared octahedral linkages are preserved.

    View details for DOI 10.1103/PhysRevLett.105.095701

    View details for Web of Science ID 000281164200012

    View details for PubMedID 20868175

  • Properties of polyamorphous Ce75Al25 metallic glasses PHYSICAL REVIEW B Zeng, Q. S., Struzhkin, V. V., Fang, Y. Z., Gao, C. X., Luo, H. B., Wang, X. D., Lathe, C., Mao, W. L., Wu, F. M., Mao, H., Jiang, J. Z. 2010; 82 (5)
  • Distortions and stabilization of simple-cubic calcium at high pressure and low temperature PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Mao, W. L., Wang, L., Ding, Y., Yang, W., Liu, W., Kim, D. Y., Luo, W., Ahuja, R., Meng, Y., Sinogeikin, S., Shu, J., Mao, H. 2010; 107 (22): 9965-9968

    Abstract

    Ca-III, the first superconducting calcium phase under pressure, was identified as simple-cubic (sc) by previous X-ray diffraction (XRD) experiments. In contrast, all previous theoretical calculations showed that sc had a higher enthalpy than many proposed structures and had an imaginary (unstable) phonon branch. By using our newly developed submicrometer high-pressure single-crystal XRD, cryogenic high-pressure XRD, and theoretical calculations, we demonstrate that Ca-III is neither exactly sc nor any of the lower-enthalpy phases, but sustains the sc-like, primitive unit by a rhombohedral distortion at 300 K and a monoclinic distortion below 30 K. This surprising discovery reveals a scenario that the high-pressure structure of calcium does not go to the zero-temperature global enthalpy minimum but is dictated by high-temperature anharmonicity and low-temperature metastability fine-tuned with phonon stability at the local minimum.

    View details for DOI 10.1073/pnas.1005279107

    View details for Web of Science ID 000278246000013

    View details for PubMedID 20479266

  • Effect of composition, structure, and spin state on the thermal conductivity of the Earth's lower mantle PHYSICS OF THE EARTH AND PLANETARY INTERIORS Goncharov, A. F., Struzhkin, V. V., Montoya, J. A., Kharlamova, S., KUNDARGI, R., Siebert, J., Badro, J., Antonangeli, D., Ryerson, F. J., Mao, W. 2010; 180 (3-4): 148-153
  • Elastic anisotropy of ferromagnesian post-perovskite in Earth's D '' layer PHYSICS OF THE EARTH AND PLANETARY INTERIORS Mao, W. L., Meng, Y., Mao, H. 2010; 180 (3-4): 203-208
  • Nanoprobe measurements of materials at megabar pressures PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Wang, L., Ding, Y., Yang, W., Liu, W., Cai, Z., Kung, J., Shu, J., Hemley, R. J., Mao, W. L., Mao, H. 2010; 107 (14): 6140-6145

    Abstract

    The use of nanoscale x-ray probes overcomes several key limitations in the study of materials up to multimegabar (> 200) pressures, namely, the spatial resolution of measurements of multiple samples, stress gradients, and crystal domains in micron to submicron size samples in diamond-anvil cells. Mixtures of Fe, Pt, and W were studied up to 282 GPa with 250-600 nm size synchrotron x-ray absorption and diffraction probes. The probes readily resolve signals from individual materials, between sample and gasket, and peak pressures, in contrast to the 5-microm-sized x-ray beams that are now becoming routine. The use of nanoscale x-ray beams also enables single-crystal x-ray diffraction studies in nominally polycrystalline samples at ultrahigh pressures, as demonstrated in measurements of (Mg,Fe)SiO(3) postperovskite. These capabilities have potential for driving a push toward higher maximum pressures and further miniaturization of high-pressure devices, in the process advancing studies at extreme conditions.

    View details for DOI 10.1073/pnas.1001141107

    View details for Web of Science ID 000276374400006

    View details for PubMedID 20304801

  • Origin of Pressure-Induced Polyamorphism in Ce75Al25 Metallic Glass PHYSICAL REVIEW LETTERS Zeng, Q., Ding, Y., Mao, W. L., Yang, W., Sinogeikin, S. V., Shu, J., Mao, H., Jiang, J. Z. 2010; 104 (10)

    Abstract

    Using high-pressure synchrotron x-ray absorption spectroscopy, we observed the Ce 4f electron in Ce(75)Al(25) metallic glass transform from its ambient localized state to an itinerant state above 5 GPa. A parallel x-ray diffraction study revealed a volume collapse of about 8.6%, coinciding with 4f delocalization. The transition started from a low-density state below 1.5 GPa, went through continuous densification ending with a high-density state above 5 GPa. This new type of electronic polyamorphism in densely packed metallic glass is dictated by the Ce constituent, and is fundamentally distinct from the well-established structural polyamorphism in which densification is caused by coordination change and atomic rearrangement.

    View details for DOI 10.1103/PhysRevLett.104.105702

    View details for Web of Science ID 000275543500032

    View details for PubMedID 20366436

  • High-pressure EXAFS study of vitreous GeO2 up to 44 GPa PHYSICAL REVIEW B Baldini, M., Aquilanti, G., Mao, H., Yang, W., Shen, G., Pascarelli, S., Mao, W. L. 2010; 81 (2)
  • New Structure and Spin State of Iron-Rich (Mg,Fe)SiO3 Post-Perovskite INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, JOINT AIRAPT-22 AND HPCJ-50 Yamanaka, T., Mao, W. L., Mao, H., Hemley, R. J., Shen, G. 2010; 215
  • Bonding in boranes and their interaction with molecular hydrogen at extreme conditions JOURNAL OF CHEMICAL PHYSICS Wang, S., Mao, W. L., Autrey, T. 2009; 131 (14)

    Abstract

    The effects of high pressure and temperature on the bonding in ammonia borane (AB), NH(3)BH(3) and decaborane (DB), B(10)H(14) and their interactions with molecular hydrogen (H(2)) were investigated using Raman spectroscopy in a diamond anvil cell. At 0.7 GPa, AB becomes amorphous between 120 and 127 degrees C, indicating a positive Clapeyron slope. Heated to 140 degrees C, AB begins to undergo decomposition to polyaminoborane. The amorphous and decomposed AB does not recrystallize back to AB during slow cooling to room temperature or upon application of high pressure up to 3 GPa, underscoring the challenge of rehydrogenation of decomposed AB. The molecular Raman modes broaden in the reacted phase, and the NH(3) modes show no pressure dependence. DB was studied at room temperature up to 11 GPa. The observed frequency dependence with pressure (dnu/dP) and mode Gruneisen parameters varied for different spectral groups, and a new transition was identified at approximately 3 GPa. In both DB and heated AB, we found that they could store additional H(2) with the application of pressure. We estimate that we can store approximately 3 wt % H(2) in heated AB at 3 GPa and 1 wt % H(2) in DB at 4.5 GPa.

    View details for DOI 10.1063/1.3244982

    View details for Web of Science ID 000270825600027

    View details for PubMedID 19831453

  • High pressure chemistry in the H-2-SiH4 system PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Wang, S., Mao, H., Chen, X., Mao, W. L. 2009; 106 (35): 14763-14767

    Abstract

    Understanding the behavior of hydrogen-rich systems at extreme conditions has significance to both condensed matter physics, where it may provide insight into the metallization and superconductivity of element one, and also to applied research areas, where it can provide guidance for designing improved hydrogen storage materials for transportation applications. Here we report the high-pressure study of the SiH4-H2 binary system up to 6.5 GPa at 300 K in a diamond anvil cell. Raman measurements indicate significant intermolecular interactions between H2 and SiH4. We found that the H2 vibron frequency is softened by the presence of SiH4 by as much as 40 cm(-1) for the fluid with 50 mol% H2 compared with pure H2 fluid at the same pressures. In contrast, the Si-H stretching modes of SiH4 shift to higher frequency in the mixed fluid compared with pure SiH4. Pressure-induced solidification of the H2-SiH4 fluid shows a binary eutectic point at 72(+/-2) mol% H2 and 6.1(+/-0.1) GPa, above which the fluid crystallizes into a mixture of two nearly end-member solids. Neither solid has a pure end-member composition, with the silane-rich solid containing 0.5-1.5 mol% H2 and the hydrogen-rich solid containing 0.5-1 mol% SiH4. These two crystalline phases can be regarded as doped hydrogen-dominant compounds. We were able to superpressurize the sample by 0.2-0.4 GPa above the eutectic before complete crystallization, indicating extended metastability.

    View details for DOI 10.1073/pnas.0907729106

    View details for Web of Science ID 000269481000008

    View details for PubMedID 19706419

  • Storage of molecular hydrogen in an ammonia borane compound at high pressure PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Lin, Y., Mao, W. L., Mao, H. 2009; 106 (20): 8113-8116

    Abstract

    We studied ammonia borane (AB), NH(3)BH(3), in the presence of excess hydrogen (H(2)) pressure and discovered a solid phase, AB(H(2))(x), where x approximately 1.3-2. The new AB-H(2) compound can store an estimated 8-12 wt % molecular H(2) in addition to the chemically bonded H(2) in AB. This phase formed slowly at 6.2 GPa, but the reaction rate could be enhanced by crushing the AB sample to increase its contact area with H(2). The compound has 2 Raman H(2) vibron peaks from the absorbed H(2) in this phase: one (nu(1)) at frequency 70 cm(-1) below the free H(2) vibron, and the other (nu(2)) at higher frequency overlapping with the free H(2) vibron at 6 GPa. The peaks shift linearly over the pressure interval of 6-16 GPa with average pressure coefficients of dnu(1)/dP = 4 cm(-1)/GPa and dnu(2)/dP = 6 cm(-1)/GPa. The formation of the compound is accompanied by changes in the N-H and B-H stretching Raman peaks resulting from the AB interactions with H(2) which indicate the structural complexity and low symmetry of this phase. Storage of significant amounts of additional molecular H(2) in AB increases the already high hydrogen content of AB, and may provide guidance for developing improved hydrogen storage materials.

    View details for DOI 10.1073/pnas.0903511106

    View details for Web of Science ID 000266209000007

    View details for PubMedID 19416809

  • X-ray diffraction studies and equation of state of methane at 202 GPa CHEMICAL PHYSICS LETTERS Sun, L., Yi, W., Wang, L., Shu, J., Sinogeikin, S., Meng, Y., Shen, G., Bai, L., Li, Y., Liu, J., Mao, H., Mao, W. L. 2009; 473 (1-3): 72-74
  • Substitutional alloy of Ce and Al PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Zeng, Q., Ding, Y., Mao, W. L., Luo, W., Blomqvist, A., Ahuja, R., Yang, W., Shu, J., Sinogeikin, S. V., Meng, Y., Brewe, D. L., Jiang, J., Mao, H. 2009; 106 (8): 2515-2518

    Abstract

    The formation of substitutional alloys has been restricted to elements with similar atomic radii and electronegativity. Using high-pressure at 298 K, we synthesized a face-centered cubic disordered alloy of highly dissimilar elements (large Ce and small Al atoms) by compressing the Ce(3)Al intermetallic compound >15 GPa or the Ce(3)Al metallic glass >25 GPa. Synchrotron X-ray diffraction, Ce L(3)-edge absorption spectroscopy, and ab initio calculations revealed that the pressure-induced Kondo volume collapse and 4f electron delocalization of Ce reduced the differences between Ce and Al and brought them within the Hume-Rothery (HR) limit for substitutional alloying. The alloy remained after complete release of pressure, which was also accompanied by the transformation of Ce back to its ambient 4f electron localized state and reversal of the Kondo volume collapse, resulting in a non-HR alloy at ambient conditions.

    View details for DOI 10.1073/pnas.0813328106

    View details for Web of Science ID 000263652900011

    View details for PubMedID 19188608

  • High-pressure induced phase transitions of Y2O3 and Y2O3:Eu3+ APPLIED PHYSICS LETTERS Wang, L., Pan, Y., Ding, Y., Yang, W., Mao, W. L., Sinogeikin, S. V., Meng, Y., Shen, G., Mao, H. 2009; 94 (6)

    View details for DOI 10.1063/1.3082082

    View details for Web of Science ID 000263409400048

  • Raman spectroscopy study of ammonia borane at high pressure JOURNAL OF CHEMICAL PHYSICS Lin, Y., Mao, W. L., Drozd, V., Chen, J., Daemen, L. L. 2008; 129 (23)

    Abstract

    Ammonia borane, NH(3)BH(3), has attracted significant interest as a promising candidate material for hydrogen storage. The effect of pressure on the bonding in NH(3)BH(3) was investigated using Raman spectroscopy to over 20 GPa in a diamond anvil cell, and two new transitions were observed at approximately 5 and 12 GPa. Vibrational frequencies for the modes of the NH(3) proton donor group exhibited negative pressure dependence, which is consistent with the behavior of conventional hydrogen bonds, while the vibrational frequencies of the BH(3) proton acceptor group showed positive pressure dependence. The observed behavior of these stretching modes supports the presence of dihydrogen bonding at high pressure. In addition, the BH(3) and NH(3) bending modes showed an increase in spectral complexity with increasing pressure together with a discontinuity in d nu/d P which suggests rotational disorder in this molecule. These results may provide guidance for understanding and developing improved hydrogen storage materials.

    View details for DOI 10.1063/1.3040276

    View details for Web of Science ID 000261896700022

    View details for PubMedID 19102540

  • Experimental determination of the elasticity of iron at high pressure JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH Mao, W. L., Struzhkin, V. V., Baron, A. Q., Tsutsui, S., Tommaseo, C. E., Wenk, H., Hu, M. Y., Chow, P., Sturhahn, W., Shu, J., Hemley, R. J., Heinz, D. L., Mao, H. 2008; 113 (B9)
  • Cubic to tetragonal phase transformation in cold-compressed Pd nanocubes NANO LETTERS Guo, Q., Zhao, Y., Mao, W. L., Wang, Z., Xiong, Y., Xia, Y. 2008; 8 (3): 972-975

    Abstract

    Pd nanocubes with an average side length of approximately 10 nm were compressed up to 24.8 GPa in a diamond-anvil cell (DAC). In situ synchrotron X-ray diffraction was used to monitor structural changes, and a face-centered cubic (fcc) to face-centered tetragonal (fct) distortion was observed for the first time. This novel discovery not only provides new insights into the pressure-induced behavior of faceted nanocrystals of palladium and other noble metals but also gives guidance for finding new phases in close-packed metals.

    View details for DOI 10.1021/nl0731217

    View details for Web of Science ID 000253947400038

    View details for PubMedID 18237151

  • Phase transformation in Sm2O3 at high pressure: In situ synchrotron X-ray diffraction study and ab initio DFT calculation SOLID STATE COMMUNICATIONS Guo, Q., Zhao, Y., Jiang, C., Mao, W. L., Wang, Z. 2008; 145 (5-6): 250-254
  • Hydrogen storage in molecular clathrates CHEMICAL REVIEWS Struzhkin, V. V., Militzer, B., Mao, W. L., Mao, H., Hemley, R. J. 2007; 107 (10): 4133-4151

    View details for DOI 10.1021/cr050183d

    View details for Web of Science ID 000249839900010

    View details for PubMedID 17850164

  • Pressure-induced cubic to monoclinic phase transformation in erbium sesquioxide Er2O3 INORGANIC CHEMISTRY Guo, Q., Zhao, Y., Jiang, C., Mao, W. L., Wang, Z., Zhang, J., Wang, Y. 2007; 46 (15): 6164-6169

    Abstract

    Cubic Er(2)O(3) was compressed in a symmetric diamond anvil cell at room temperature and studied in situ using energy-dispersive X-ray diffraction. A transition to a monoclinic phase began at 9.9 GPa and was complete at 16.3 GPa and was accompanied by a approximately 9% volume decrease. The monoclinic phase was stable up to at least 30 GPa and could be quenched to ambient conditions. The normalized lattice parameter compression data for both phases were fit to linear equations, and the volume compression data were fit to third-order Birch-Murnaghan equations of state. The zero-pressure isothermal bulk moduli (B(0)) and the first-pressure derivatives (B(0)') for the cubic and monoclinic phases were 200(6) GPa and 8.4 and also 202(2) GPa and 1.0, respectively. Ab initio density functional theory calculations were performed to determine optimized lattice parameters and atom positions for the cubic, monoclinic, and hexagonal phases of Er(2)O(3). The calculated X-ray spectra and predicted transition pressure are in good qualitative agreement with the experimental results.

    View details for DOI 10.1021/ic070154g

    View details for Web of Science ID 000248011300046

    View details for PubMedID 17595073

  • Pressure-induced distortive phase transition in chromite-spinel at 29 GPa MATERIALS RESEARCH AT HIGH PRESSURE Shu, J., Mao, W. L., Hemley, R. J., Mao, H. 2007; 987: 179-184
  • Effect of iron on the properties of post-perovskite silicate, The Last Mantle Phase Transition Mao, W. L., Campbell , A. J., Prakapenka, V. B., Hemley , R. J., H-k. Mao , H. edited by Hirose, K., Brodholt, J., Lay, T., Yuen, D. American Geophysical Union. 2007: 37-46
  • Diamond Anvil Cells and Ultra-High P/T Experimental Methods Treatise on Geophysics Mao, H., Mao, W. L. edited by Price, G. D. Elsevier, Amsterdam. 2007: 231-267
  • High-P/Low-T Neutron Scattering of Hydrogen Inclusion Compounds-Progress and Prospects Proceedings of the National Academy of Sciences Zhao, Y., Xu, H., Daemen, L. L., Lokshin, K., Mao, W. L., Luo, J., Currier, R. P., Hickmott, D. D. 2007; 104: 5727-5731
  • Clathrate hydrates under pressure Physics Today Mao, W. L., Koh, C. A., Sloan, E. D. 2007; 60: 42-47
  • X-ray-induced dissociation of H2O and formation of an O-2-H-2 alloy at high pressure SCIENCE Mao, W. L., Mao, H., Meng, Y., Eng, P. J., Hu, M. Y., Chow, P., Cai, Y. Q., Shu, J., Hemley, R. J. 2006; 314 (5799): 636-638

    Abstract

    When subjected to high pressure and extensive x-radiation, water (H2O) molecules cleaved, forming O-O and H-H bonds. The oxygen (O) and hydrogen (H) framework in ice VII was converted into a molecular alloy of O2 and H2. X-ray diffraction, x-ray Raman scattering, and optical Raman spectroscopy demonstrated that this crystalline solid differs from previously known phases. It remained stable with respect to variations in pressure, temperature, and further x-ray and laser exposure, thus opening new possibilities for studying molecular interactions in the hydrogen-oxygen binary system.

    View details for DOI 10.1126/science.1132884

    View details for Web of Science ID 000241557800043

    View details for PubMedID 17068259

  • The effect of pressure on the structure and volume of ferromagnesian post-perovskite GEOPHYSICAL RESEARCH LETTERS Mao, W. L., Mao, H. K., Prakapenka, V. B., Shu, J. F., Hemley, R. J. 2006; 33 (12)
  • Iron-rich post-perovskite and the origin of ultralow-velocity zones SCIENCE Mao, W. L., Mao, H. K., Sturhahn, W., Zhao, J. Y., Prakapenka, V. B., Meng, Y., Shu, J. F., Fei, Y. W., Hemley, R. J. 2006; 312 (5773): 564-565

    Abstract

    The boundary layer between the crystalline silicate lower mantle and the liquid iron core contains regions with ultralow seismic velocities. Such low compressional and shear wave velocities and high Poisson's ratio are also observed experimentally in post-perovskite silicate phase containing up to 40 mol% FeSiO3 endmember. The iron-rich post-perovskite silicate is stable at the pressure-temperature and chemical environment of the core-mantle boundary and can be formed by core-mantle reaction. Mantle dynamics may lead to further accumulation of this material into the ultralow-velocity patches that are observable by seismology.

    View details for DOI 10.1126/science.1123442

    View details for Web of Science ID 000237296700041

    View details for PubMedID 16645091

  • Ultrahigh pressure experiment with a motor-driven diamond anvil cell Journal of Physics: Condensed Matter Mao, W., Mao, H. 2006; 18: S1069-S1073
  • Phase relations in Fe-Ni alloys at high pressure and temperature Physics of the Earth and Planetary Interiors Mao, W. L., Campbell, A. J., Heinz, D. L., Shen, G. 2006; 155: 146-151
  • Iron-rich silicates in the Earth's D '' layer PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Mao, W. L., Meng, Y., Shen, G. Y., Prakapenka, V. B., Campbell, A. J., Heinz, D. L., Shu, J. F., Caracas, R., Cohen, R. E., Fei, Y. W., Hemley, R. J., Mao, H. K. 2005; 102 (28): 9751-9753

    Abstract

    High-pressure experiments and theoretical calculations demonstrate that an iron-rich ferromagnesian silicate phase can be synthesized at the pressure-temperature conditions near the core-mantle boundary. The iron-rich phase is up to 20% denser than any known silicate at the core-mantle boundary. The high mean atomic number of the silicate greatly reduces the seismic velocity and provides an explanation to the low-velocity and ultra-low-velocity zones. Formation of this previously undescribed phase from reaction between the silicate mantle and the iron core may be responsible for the unusual geophysical and geochemical signatures observed at the base of the lower mantle.

    View details for DOI 10.1073/pnas.0503737102

    View details for Web of Science ID 000230545100005

    View details for PubMedID 15994226

  • Pressure-temperature stability of the van der Waals compound (H-2)(4)CH4 CHEMICAL PHYSICS LETTERS Mao, W. L., Struzhkin, V. V., Mao, H. K., Hemley, R. J. 2005; 402 (1-3): 66-70
  • The stability and Raman spectra of ikaite, CaCO3•6H2O, at high pressure and temperature American Mineralogist Shahar, A., Bassett, W., Mao, H., Chou, I., Mao, W. 2005; 90: 1835-1839
  • Ferromagnesian postperovskite silicates in the D '' layer of the Earth PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Mao, W. L., Shen, G. Y., Prakapenka, V. B., Meng, Y., Campbell, A. J., Heinz, D. L., Shu, J. F., Hemley, R. J., Mao, H. K. 2004; 101 (45): 15867-15869

    Abstract

    Natural olivine with 12 mol % Fe(2)SiO(4) and synthetic orthopyroxenes with 20% and 40% FeSiO(3) were studied beyond the pressure-temperature conditions of the core-mantle boundary. All samples were found to convert entirely or partially into the CaIrO(3) postperovskite structure, which was recently reported for pure MgSiO(3). The incorporation of Fe greatly reduces the pressure needed for the transition and establishes the new phase as the major component of the D'' layer. With the liquid core as an unlimited reservoir of iron, core-mantle reactions could further enrich the iron content in this phase and explain the intriguing seismic signatures observed in the D'' layer.

    View details for DOI 10.1073/pnas.0407135101

    View details for Web of Science ID 000225196800010

    View details for PubMedID 15520393

  • Structure and dynamics of hydrogen molecules in the novel clathrate hydrate by high pressure neutron diffraction PHYSICAL REVIEW LETTERS Lokshin, K. A., Zhao, Y. S., He, D. W., Mao, W. L., Mao, H. K., Hemley, R. J., Lobanov, M. V., Greenblatt, M. 2004; 93 (12)

    Abstract

    The D2 clathrate hydrate crystal structure was determined as a function of temperature and pressure by neutron diffraction for the first time. The hydrogen occupancy in the (32+X)H2.136H(2)O, x=0-16 clathrate can be reversibly varied by changing the large (hexakaidecahedral) cage occupancy between two and four molecules, while remaining single occupancy of the small (dodecahedral) cage. Above 130-160 K, the guest D2 molecules were found in the delocalized state, rotating around the centers of the cages. Decrease of temperature results in rotation freezing followed by a complete localization below 50 K.

    View details for DOI 10.1103/PhysRevLett.93.125503

    View details for Web of Science ID 000223923800044

    View details for PubMedID 15447276

  • Nuclear resonant x-ray scattering of iron hydride at high pressure GEOPHYSICAL RESEARCH LETTERS Mao, W. L., Sturhahn, W., Heinz, D. L., Mao, H. K., Shu, J. F., Hemley, R. J. 2004; 31 (15)
  • Hydrogen storage in molecular compounds PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Mao, W. L., Mao, H. K. 2004; 101 (3): 708-710

    Abstract

    At low temperature (T) and high pressure (P), gas molecules can be held in ice cages to form crystalline molecular compounds that may have application for energy storage. We synthesized a hydrogen clathrate hydrate, H(2)(H(2)O)(2), that holds 50 g/liter hydrogen by volume or 5.3 wt %. The clathrate, synthesized at 200-300 MPa and 240-249 K, can be preserved to ambient P at 77 K. The stored hydrogen is released when the clathrate is warmed to 140 K at ambient P. Low T also stabilizes other molecular compounds containing large amounts of molecular hydrogen, although not to ambient P, e.g., the stability field for H(2)(H(2)O) filled ice (11.2 wt % molecular hydrogen) is extended from 2,300 MPa at 300 K to 600 MPa at 190 K, and that for (H(2))(4)CH(4) (33.4 wt % molecular hydrogen) is extended from 5,000 MPa at 300 K to 200 MPa at 77 K. These unique characteristics show the potential of developing low-T molecular crystalline compounds as a new means for hydrogen storage.

    View details for Web of Science ID 000188555400004

    View details for PubMedID 14711993

  • Phonon density of states and elastic properties of Fe-based materials under compression HYPERFINE INTERACTIONS Struzhkin, V. V., Mao, H. K., Mao, W. L., Hemley, R. J., Sturhahn, W., Alp, E. E., L'abbe, C., Hu, M. Y., Errandonea, D. 2004; 153 (1-4): 3-15
  • Generation of ultrahigh pressure using single-crystal chemical-vapor-deposition diamond anvils APPLIED PHYSICS LETTERS Mao, W. L., Mao, H. K., Yan, C. S., Shu, J. F., Hu, J. Z., Hemley, R. J. 2003; 83 (25): 5190-5192

    View details for DOI 10.1063/1.1636270

    View details for Web of Science ID 000187341800024

  • Bonding changes in compressed superhard graphite SCIENCE Mao, W. L., Mao, H. K., Eng, P. J., Trainor, T. P., Newville, M., Kao, C. C., Heinz, D. L., Shu, J. F., Meng, Y., Hemley, R. J. 2003; 302 (5644): 425-427

    Abstract

    Compressed under ambient temperature, graphite undergoes a transition at approximately 17 gigapascals. The near K-edge spectroscopy of carbon using synchrotron x-ray inelastic scattering reveals that half of the pi-bonds between graphite layers convert to sigma-bonds, whereas the other half remain as pi-bonds in the high-pressure form. The x-ray diffraction pattern of the high-pressure form is consistent with a distorted graphite structure in which bridging carbon atoms between graphite layers pair and form sigma-bonds, whereas the nonbridging carbon atoms remain unpaired with pi-bonds. The high-pressure form is superhard, capable of indenting cubic-diamond single crystals.

    View details for Web of Science ID 000185963200036

    View details for PubMedID 14564003

  • Displacive transition in magnesiowustite JOURNAL OF PHYSICS-CONDENSED MATTER Mao, W. L., Shu, J. F., Hu, J. Z., Hemley, R., Mao, H. 2002; 14 (44): 11349-11354
  • Hydrogen clusters in clathrate hydrate SCIENCE Mao, W. L., Mao, H. K., Goncharov, A. F., Struzhkin, V. V., Guo, Q. Z., Hu, J. Z., Shu, J. F., Hemley, R. J., Somayazulu, M., Zhao, Y. S. 2002; 297 (5590): 2247-2249

    Abstract

    High-pressure Raman, infrared, x-ray, and neutron studies show that H2 and H2O mixtures crystallize into the sII clathrate structure with an approximate H2/H2O molar ratio of 1:2. The clathrate cages are multiply occupied, with a cluster of two H2 molecules in the small cage and four in the large cage. Substantial softening and splitting of hydrogen vibrons indicate increased intermolecular interactions. The quenched clathrate is stable up to 145 kelvin at ambient pressure. Retention of hydrogen at such high temperatures could help its condensation in planetary nebulae and may play a key role in the evolution of icy bodies.

    View details for Web of Science ID 000178222000043

    View details for PubMedID 12351785

  • Iron-nickel alloy in the Earth's Core Geophysical Research Letters Lin, J., Heinz, D., Campbell, A., Devine, J., Mao, W., Shen, G. 2002; 29

    View details for DOI 10.1029/2002GL015089