Ilana Jessica Porter Molesky
Postdoctoral Scholar, Photon Science, SLAC
Professional Education
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Bachelor of Science, Massachusetts Institute of Technology (2016)
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Doctor of Philosophy, University of California Berkeley (2022)
All Publications
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Coherent Phonons in Antimony: An Undergraduate Physical Chemistry Solid-State Ultrafast Laser Spectroscopy Experiment
JOURNAL OF CHEMICAL EDUCATION
2022
View details for DOI 10.1021/acs.jchemed.2c00816
View details for Web of Science ID 000888146000001
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Characterization of Carrier Cooling Bottleneck in Silicon Nanoparticles by Extreme Ultraviolet (XUV) Transient Absorption Spectroscopy
JOURNAL OF PHYSICAL CHEMISTRY C
2021; 125 (17): 9319-9329
View details for DOI 10.1021/acs.jpcc.1c02101
View details for Web of Science ID 000648873500042
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Electron thermalization and relaxation in laser-heated nickel by few-femtosecond core-level transient absorption spectroscopy
PHYSICAL REVIEW B
2021; 103 (6)
View details for DOI 10.1103/PhysRevB.103.064305
View details for Web of Science ID 000617038600001
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Layer-resolved ultrafast extreme ultraviolet measurement of hole transport in a Ni-TiO<sub>2</sub>-Si photoanode
SCIENCE ADVANCES
2020; 6 (14): eaay6650
Abstract
Metal oxide semiconductor junctions are central to most electronic and optoelectronic devices, but ultrafast measurements of carrier transport have been limited to device-average measurements. Here, charge transport and recombination kinetics in each layer of a Ni-TiO2-Si junction is measured using the element specificity of broadband extreme ultraviolet (XUV) ultrafast pulses. After silicon photoexcitation, holes are inferred to transport from Si to Ni ballistically in ~100 fs, resulting in characteristic spectral shifts in the XUV edges. Meanwhile, the electrons remain on Si. After picoseconds, the transient hole population on Ni is observed to back-diffuse through the TiO2, shifting the Ti spectrum to a higher oxidation state, followed by electron-hole recombination at the Si-TiO2 interface and in the Si bulk. Electrical properties, such as the hole diffusion constant in TiO2 and the initial hole mobility in Si, are fit from these transient spectra and match well with values reported previously.
View details for DOI 10.1126/sciadv.aay6650
View details for Web of Science ID 000523302400013
View details for PubMedID 32284972
View details for PubMedCentralID PMC7124930
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Differentiating Photoexcited Carrier and Phonon Dynamics in the Δ, <i>L</i>, and Γ Valleys of Si(100) with Transient Extreme Ultraviolet Spectroscopy
JOURNAL OF PHYSICAL CHEMISTRY C
2019; 123 (6): 3343-3352
View details for DOI 10.1021/acs.jpcc.8b10887
View details for Web of Science ID 000459223200011
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Real-Time Observation of a Coherent Lattice Transformation into a High-Symmetry Phase
PHYSICAL REVIEW X
2018; 8 (3)
View details for DOI 10.1103/PhysRevX.8.031081
View details for Web of Science ID 000445601800003
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Photoexcited Small Polaron Formation in Goethite (α-FeOOH) Nanorods Probed by Transient Extreme Ultraviolet Spectroscopy
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
2018; 9 (14): 4120-4124
Abstract
Small polaron formation limits the mobility and lifetimes of photoexcited carriers in metal oxides. As the ligand field strength increases, the carrier mobility decreases, but the effect on the photoexcited small polaron formation is still unknown. Extreme ultraviolet transient absorption spectroscopy is employed to measure small polaron formation rates and probabilities in goethite (α-FeOOH) crystalline nanorods at pump photon energies from 2.2 to 3.1 eV. The measured polaron formation time increases with excitation photon energy from 70 ± 10 fs at 2.2 eV to 350 ± 30 fs at 2.6 eV, whereas the polaron formation probability (85 ± 10%) remains constant. By comparison to hematite (α-Fe2O3), an oxide analogue, the role of ligand composition and metal center density in small polaron formation time is discussed. This work suggests that incorporating small changes in ligands and crystal structure could enable the control of photoexcited small polaron formation in metal oxides.
View details for DOI 10.1021/acs.jpclett.8b01525
View details for Web of Science ID 000448083300047
View details for PubMedID 29985006